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Because of the great practical importance of and increasing demand for the alkenes formed in the dehydrogenation of alkanes, significant attention is still devoted to the fundamental aspects of the catalytic and oxidative dehydrogenation of alkanes to alkenes Numerous reports were published, new catalysts were reported, and basic questions such as C-H bond activation, active sites and mechanistic problems were addressed The possibility of using CO 2 as oxidizing agent in the dehydrogenation of ethylbenzene to styrene is gaining importance General reviews of the subject with respect to thermal and catalytic dehydrogenations 317 as well as oxidative dehydrogenation 318 ,319 are available Only selected aspects of the most recent significant developments in the dehydrogenative formation of alkenes of practical importance, namely, ethylene, propylene, butenes, 1,3-butadiene, and styrene, are discussed here Catalytic Dehydrogenation.



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The types of biochemical and genetic studies described above have been extended to each of the biogeochemical processes shown in Figures 713 715 and listed in Table 74 Consequently there is an enormous amount of scienti c information available about physiological, biochemical, and genetic mechanisms of microbially mediated reactions As an example, Table 76 provides a listing of many microbial systems and their enzymes that catalyze nitrogen cycling The anatomy of discovery: anaerobic oxidation of ammonia and methane As was discussed in 6 (Sections 66 and 610), selecting an ecologically important model organism as a source of biochemical and genetic information is a challenge That challenge was met exceptionally well in two recent and remarkably successful cases that each uncovered and characterized microbial processes of global signi cance: anaerobic.





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Reviews are available for chromium-based dehydrogenation catalysts, particularly the industrial chromia-alumina used for the dehydrogenation of propane and isobutane,320 and more recent advances in research and development of commercial catalysts for ethylbenzene dehydrogenation 21 Studies analyze catalyst deactivation phenomena in styrene production over iron oxide catalysts,322 and report the development of a new styrene production cataIYSt 321 Comparative analyses of various processes used in propylene production, namely, the nonoxidative dehydrogenation process of UOP and autothermal and isothermal oxidative dehydrogenations,323 and in the production of styrene were reported 324 A new technology, called the SMART process, a combination of the Lummus process with UOP concept for oxidative reheating by selective catalytic oxidation of hydrogen, was developed for styrene production This concept was further explored by using a combination of mixed oxides for selective hydrogen combustion and a 0.

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7% Pt-Sn-on-ZSM-5 catalyst for dehydrogenation 25 New results of styrene formation over iron oxide single-crystal model catalysts were reported 26 In ultra-high-vacuum experiments with Fe304(1l1) and cx-Fe203(0001) films combined with batch reaction studies only Fe203 showed catalytic activity The activity increased with increasing surface defect.

rest. Yalom (1985) speci es that the self-disclosure may involve past or current events in one s life, fantasy or dream material, hopes or aspirations for the future, and current feelings toward other individuals (p. 360). As with any art therapy interaction, the active leader stance produces total group communication, from the individual creation to the processilluminating questions; focus on a group-centered model is always foremost. For this individual and collective group investment promotes a sense of community, understanding, and intimacy, which we hope will be generalized into the larger environment. Figure 6.18 is an example of a disclosure that produced both group understanding and reality-based discussions surrounding xed false beliefs. Recall Figure 6.1. This depressed adult had a propensity to render his drawings in black, devoid of adequate detailing. Additionally, he only found success or glory through his delusional religious beliefs. Thus, his moodincongruent psychotic features and his symbolic renderings afforded him a

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