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The polyenic sequences are readily photooxidized in the presence of molecular oxygen. Reactions proceed primarily by a free-radical chain mechanism leading to chain scission (C C bond cleavage) and crosslinking and result in deterioration of the mechanical and electrical properties. Photooxidation of the polyene sequences is accompanied by photobleaching, the extent depending on the emission spectrum of the light source [45]. Sources that emit only a narrow range of UV wavelengths and no visible radiation cannot excite all the polyene sequences and effect less photobleaching. Photooxidation also takes place via reaction of oxygen with the chlorine free radicals formed when the allylic C Cl bonds cleave. Due to the slow diffusion of oxygen into PVC, weathering is primarily restricted to the surface layers. Oxidation products develop only to a depth of about 200 m from the surface, whereas polyenes are formed to a depth of about 400 m [46]. The latter act as UV absorbers, shielding the bulk of the polymer from UV radiation. Progressive destruction of surface layers results in loss of gloss, embrittlement, and loss of impact strength. In impact PVC (ABS, MBS, or MABS modi ed), rapid photooxidation of the elastomer component is observed, leading to an acceleration of PVC degradation [47]. In exible PVC, the loss of plasticizer during weathering results in property deterioration. In contrast to some other polymeric materials, moisture is not an important factor in the degradation of PVC itself. However, the effect of moisture on additives can be a signi cant factor in the weathering of PVC. For example, the photocatalytical activity of titanium dioxide in TiO2 -pigmented PVC exposed outdoors depends on the presence and amount of rain.



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In the event that the B response is negative, Equations 14.29 is replaced with Equations 14.31 to avoid taking a root of a negative number. Br = [D(B0r/B ) + 1 D]| B | 0 (14.31)

2.6 HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC)





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Throughout this book, emphasis has been placed on the ability to pass data over the network without error So what is network data integrity It is the guarantee that data sent to an intended network node arrives without alternation The other part is that if the data being sent is of a sensitive nature, it needs to be safeguarded and not eavesdropped upon as it traverses over the network One method, as previously mentioned, is to secure the premises and not allow unauthorized personnel into areas where the network could be easily snooped The other method is to safeguard data with encryption Encryption encodes the data being transmitted over the network in such a manner that only the two endpoints of the network connection are able to decrypt the data.

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This was initially performed by sharing a known key7 between the two endpoints, which was used to encrypt the data that was sent and decrypt the received data to make it readable Figure 14-5 illustrates an example of sharing a key between two endpoint network nodes Rob and Jack want to share sensitive information over the network The network can include the Internet and any other portions of network, whether public or private To accomplish this, they decide to encrypt the data before sending it over the network They settle on an application that allows them to use a shared key between them This is secure only if they are the only two people who know what the key contains However, they should not send the key over the same network link.

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If Rob and Jack are unable to meet privately and the key needs to be carried over a public network, they need to be cautious not to give the people who may be snooping their communications the key along with the encrypted document It would be better for them to mail the key through the post of ce than to e-mail it Or they could simply call each other to pass along the key The only caveat is that with the convergence of voice and data on the organization s network, if the phone service is one and the same as the data network, then there is no security for Rob calling Jack.

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