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331 T Yamamoto and M Kimura, l Chern Soc, Chern Cornrnun 948 (1977) 332 T Katsuki and K B Sharpless, l Arn Chern Soc 102,5974 (1980) 333 A Pfenninger, Synthesis 89 (1986) 334 R A Johnson and K B Sharpless, in Cornprehensive Organic Synthesis, B M Trost and 1 Fleming, eds, Vo!' 7: Oxidation, S V Ley, ed, Pergamon Press, Oxford, 1991, 32, p 389 335 K Tani, M Hanafusa, and S Otsuka, Tetrahedron Lett 3017 (1979) 336 C Bolm, Angew Chern, Int Ed Engl 30,403 (1991) 337 E Haft, Top Curro Chern 164,63 (1993) 338 V Schurig, K Hintzer, U Leyrer, C Mark, P Pitchen, and H B Kagan, l Organornet Chern 370, 81 (1989) 339 H B Kagan, H Mimoun, C Mark, and V Schurig, Angew Chern, Int Ed Engl 18, 485 (1979) 340 F A Davis and S Chattopadhyay, Tetrahedron Lett.



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You were introduced to a few of the features of FeedBurner in the previous chapter with an eye toward splicing your bookmark posting stream into your feeds, as well as for building sidebar lists from your links. Another relatively new feature from FeedBurner called FeedFlare takes things in the opposite direction. With FeedFlare activated for one of your feeds, FeedBurner can inject Add to del.icio.us links into items. These links are visible in the feed readers of your subscribers, available for quick access from most aggregators. If you haven t already, pay a visit to FeedBurner and set up one of your feeds for burning here:





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and the packets are returned to the sender. This procedure allows to measure the response time and the percentage of packet losses. FTP: This is the simplest application for transferring files from one host to another, and is commonly used for measurement of the transfer rates. It is important to note that relatively big-sized files should be used in order to obtain an accurate estimation of the bit rate. The reason is that in every FTP session there are a number of constants delays due to the establishment time of the connection and start up delays of the TCP (slow start), which should be minimized in comparison to the real transfer time. Traceroute: This application is similar to ping, and also uses the transmission of ICMP packets to measure the delays between all the hops involved in the transmission from the client host to the service provider.

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27, 5079 (1986) 341 J T Groves and P Viski, l Org Chern 55, 3628 (1990) 342 Y Naruta, F Tani, N Ishihara, and K Maruyama, l Arn Chern Soc 113, 6865 (1991) 343 Y Naruta, N Ishihara, F Tani, and K Maruyama, Bull Chern Soc lpn 66,158 (1993) 344 R Irie, K Noda, Y Ito, N Matsumoto, and T Katsuki, Tetrahedron Lett 31, 7345 (1990) 345 W Zhang, J L Loebach, S R Wilson, and E N Jacobsen, l Arn Chern Soc 112, 2801 (1990) 346 W Zhang and E N Jacobsen, l Org Chern 56, 2296 (1991) 347 T Yamada, K Imagawa, T Nagata, and T Mukaiyama, Chern Lett 2231 (1992) 348 S W May, M S Steltenkamp, R D Schwartz, and C J McCoy, l Arn Chern Soc 98, 7856 (1976) 349 M-J de Smet, B Witholt, and H Wynberg, l Org Chern 46, 3128 (1981).

reacts with inversion. The involvement of a cyclic halonium ion intermediate ensures retention of configuration in alkylation with (S)-l,4-dichloropentane. An important application of alkylation with di- and polyhalides is cyclialkylative ring formation. Of different cx,w-dihaloalkanes studied, l,4-dichlorobutane was shown to react at exceptional rate and with least rearrangement. 143 This was rationalized in terms of participation by the cyclic chloronium ion 29 formed with anchimeric assistance by the second chlorine atom in the molecule:

N OT E Inner and outer fields are only relevant in the Row Labels and Column Labels areas; there is no such type of relationship in the Report Filter area or the Values area of a PivotTable report.

350 V Schurig and D Wistuba, Angew Chern, Int Ed Engl 23, 796 (1984) 351 H Ohta and H Tetsukawa, l Chern Soc, Chern Cornrnun 849 (1978) 352 O Takahashi, J Umezawa, K Furuhashi, and M Takagi, Tetrahedron Lett 30, 1583 (1989) 353 E J Allain, L P Hager L Deng, and E N Jacobsen, l Arn Chern Soc 115,4415 (1993) 354 W Adam and M J Richter, Acc Chern Res 27, 57 (1994) 355 E S Huyser, Free-Radical Chain Reactions, Wiley-Interscience, New York, 1970, 11, p 293 356 V V Voronenkov, A N Vinogradov, and V A Belyaev, Russ Chern Rev (Eng! trans!) 39, 944 (1970) 357 1 Rosenthal, in Singlet 020 Vo!' 1: Physical-Chernical Aspects, A A Frimer, ed, CRC Press, Boca Raton, FL, 1985, 2, p 13 358 R W Murray, in Singlet Oxygen, H H Wasserman and R W Murray, eds.

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