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enthalpies of complexation determined ( 7X6 and 14X5 kJ/mol, respectively). Why is it reasonable that the second CO binds almost as strongly as the rst 11. Dative bonded complexes between alane (AlH3 ) and amines have long been known. Complexes with one and two amines are common. For example, bis-(trimethylamine) alane, AlH3 (N(CH3 )3 )2 , is a white crystalline solid with a low vapor pressure. Using ammonia as a model for trimethylamine, apply orbital interaction analysis to describe the bonding in the 1 : 1 and 1 : 2 complexes. Theoretical studies on the ammonia complexes of AlH3 have led to the conclusion that there is little dative bonding (as judged by the amount of charge transfer) (Marsh, C. M. B.; Schaefer III, H. F., J. Phys. Chem., 1995, 99, 14309 14315). Comment on the theoretical results. 12. Use orbital interaction diagrams to explain each of the following (show the orbitals clearly): (a) Describe the N N bond in hydrazinium dichloride, H3 N N H3 2Cl . (b) Account for the fact that trans-2,5-dichloro-1,4-dioxane 4 preferentially adopts the diaxial conformation (Koritsanszky, T.; Strumpel, M. K.; Buschmann, J.; Luger, P.; Hansen, N. K.; PichonPesme, V., J. Am. Chem. Soc., 1991, 113, 9148). Hint: This is an example of the anomeric e ect in operation.



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Fig. 2.2 Array signal model for a two-element array. d = distance between elements, 0 = angle of arrival of wave from boresight, Ad = additional distance of wave.

Halftone Screen: When you select this option from the Use pop-up menu and press Enter, Photoshop displays the dialog box shown in Figure 4-7. These options enable you to apply a dot pattern to the image, as demonstrated in Figure 4-8. Enter the number of dots per inch in the Frequency option box and the angle of the dots in the Angle option box. Then select a dot shape from the Shape pop-up menu. Figure 4-8 shows examples of four shapes, each with a frequency of 24 lines per inch.

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Arc: Draws arcs This option opens up a set of arc suboptions, which are explained next, after this list Close: Closes a polyline by drawing a line from the endpoint of the last line segment to the start point of the polyline This option appears only after you ve picked a second point Halfwidth: Defines half of the width of the polyline the distance from the center of the polyline to its edge The option asks you for the starting halfwidth and the ending halfwidth, enabling you to create polylines that are tapered Length: Specifies the length of the next line segment The option draws the line segment in the same direction as the last line segment or tangent to the last arc Undo: Undoes the last line segment Width: Defines the width of the polyline The option asks you for the starting width and the ending width.

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where z(m, n) = z ( ( m- 1)(N P ) n) stands for the nth sample of the mth received pilot symbol. Since the pilot contains M identical symbols, i.e.

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Specify next point: Enables you to create a line segment This is the default option Like the LINE command, PLINE continues to prompt you for more points, repeating the entire prompt each time When you re done, press Enter to end the command If you choose Arc, you see the Specify endpoint of arc or [Angle/CEnter/CLose/ Direction/Halfwidth/Line/Radius/Second pt/ Undo/Width]: prompt Although this may seem overwhelming, most of the options are similar to the ARC command options If you need a review, see Drawing Arcs in 7 The arc options are as follows: Angle: Specifies the included angle CEnter: Specifies the arc s center CLose: Closes the polyline by drawing an arc from the endpoint of the last arc to the start point of the polyline Direction: Specifies the direction of the arc from the start point.

[1] MA Alsunaidi, SM Sohel Imtiaz, SM El-Ghazaly, Electromagnetic wave effects on microwave transistors using a full-wave time domain model , IEEE Trans Microwave Theory Tech, 44(6), 799 807, 1996 [2] S Datta, Electronic Transport in Mesoscopic Systems, Cambridge University Press, Cambridge (UK), 1995 [3] K Bl tekj r, Transport equations for electrons in two-valley semiconductors , IEEE Trans Electron Devices, ED-17, 38 47, 1970 [4] S Selberherr, Analysis and Simulation of Semiconductor Devices, Springer-Verlag, Wien, New York (NY), 1984 [5] B Troyanovsky, Z-P Yu, RW Dutton, Physics-based simulation of nonlinear distortion in semiconductor devices using the harmonic balance method , Comput Methods Appl Mech Eng, 181, 467 482, 2000 [6] T Shawki, G Salmer, O El Sayed, MODFET 2-D hydrodynamic energy modelling: optimisation of subquarter-micron-gate structures , IEEE Trans Electron Devices, 37, 21 29, 1990 [7] CM Snowden, D.

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