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The radical 1,4-polymerization of certain diacetylenes (conjugated dialkynes) proceeds to yield high-molecular-weight polymer (105 ) when carried out in the solid state. Diacetylene itself has not been successfully polymerized; it is too reactive to be polymerized in a controlled manner. 1,4-Disubstituted diacetylenes are polymerized by ionizing radiation, UV, or heat [Chance, 1986; Hoofman et al., 2001]. The reaction proceeds via a dicarbene propagating species (LXI) with the nal product possessing an alternating ene-yne-conjugated

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structure (LXII). Among the diacetylenes studied are those in which R is CH2 OSO2 fCH3 , (CH2 4 OCONHCH2 COOC4 H9 , and (CH2 4 OCONHf. High-molecular-weight polymer is obtained only when the reaction proceeds as a lattice-controlled (topochemical) solid-state polymerization. This occurs only when the R groups have the appropriate bulk such that the diacetylene monomer and corresponding polymer have essentially the same crystal structure. The topochemical reaction transforms a monomer crystal to a polymer crystal with similar dimensions. Polymer single crystals of macroscopic dimensions, several centimeters in some cases, have been synthesized. The conjugated p-electron system of the polydiacetylenes imparts intense light absorption in the visible region as well as interesting (photo)conductivity and nonlinear optical properties.

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Abuin, E. and E. A. Lissi, J. Macromol. Sci. Chem., A11, 287 (1977). Abuin, E. B., E. A. Lissi, and A. Marquez, J. Polym. Sci. Polym. Chem. Ed., 16, 3003 (1978). Adelman, R. L. and R. C. Ferguson, J. Polym. Sci. Polym. Chem. Ed., 13, 891 (1975). Allen, P. E. M. and C. R. Patrick, Kinetics and Mechanisms of Polymerization Reactions, Chaps. 2 4, 7, Wiley, New York, 1974. Amdur, S., A. T. Y. Cheng, C. J. Wong, P. Ehrlich, and R. D. Allendoefer, J. Polym. Sci. Polym. Chem. Ed., 16, 407 (1978). Ananchenko, G. S. and H. Fischer, J. Polym. Sci. Polym. Chem. Ed., 39, 3604 (2001). Aquilar, M. R., A. Gallardo, M. del Mar Fernandez, and J. San Roman, Macromolecules, 35, 2036 (2002). Archer, R. D., Inorganic and Organometallic Polymers, Wiley-VCH, New York, 2001. Areizaga, J. F. and G. M. Guzman, Makromol. Chem. Macromol. Symp. 20/21, 77 (1988). Arnett, L. M. and J. H. Peterson, J. Am. Chem. Soc., 74, 2031 (1952).

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To control the number of decimal places that appear in numeric data, select the cell or range that you want to format. Click the Home tab on the Ribbon. Click Increase Decimal ( ) or Decrease Decimal ( ).

Arpe, H-J, Ullmann s Encyclopedia of Industrial Chemistry, Wiley, New York, 2002 (online version), 1996 (hardcopy) Asano, T and W J Le Noble, Chem Rev, 78, 407 (1978) Axelson, D E, G C Levy, and L Mandelkern, Macromolecules, 12, 41 (1979) Ayrey, G and A C Haynes, Makromol Chem, 175, 1463 (1974) Ayrey, G, M J Humphrey, and R C Poller, Polymer, 18, 840 (1977) Backsai, R, J Polym Sci Polym Chem Ed, 14, 1797 (1976) Bajaj, P and S Kumari, J Macromol Sci- Rev Macromol Chem Phys, C27, 181 (1987) Baker, C, P David, and W F Maddams, Makromol Chem, 180, 975 (1979) Balakrishnan, T and S Subbu, J Polym Sci Polym Chem Ed, 26, 355 (1988) Balke, S T and A E Hamielec, J Appl Polym Sci, 17, 905 (1973) Bamford, C H.

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, Radical Polymerization, pp 708 867 in Encyclopedia of Polymer Science and Engineering, Vol 13, H F Mark, N M Bikales, C G Overberger, and G Menges, eds, WileyInterscience, New York, 1988 Bamford, C H, R W Dyson, and G C Eastward, Polymer, 10, 885 (1969a) Bamford, C H, G C Eastmond, and D Whittle, Polymer, 10, 771 (1969b) Bando, Y and Y Minoura, J Polym Sci Polym Chem Ed, 14, 1183, 1195 (1976) Barb, W G, J H Baxendale, P George, and K R Hargrave, Trans Faraday Soc, 47, 462, 591 (1951) Barner-Kowollik, C, J F Quinn, and D R Morsley, J Polym Sci Polym Chem Ed, 39, 1353 (2001) Barner-Kowollik, C, T P Davis, J P A Heuts, M H Stenzel, P Vana, and M Whittaker, J Polym Sci Polym Chem Ed, 41, 365 (2003) Barr, N J.

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