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An insigni cant amount (approximately <01%) of polymer is found in the monomer droplets in such experiments Polymerization takes place almost exclusively in the micelles Monomer droplets do not compete effectively with micelles in capturing radicals produced in solution because of the much smaller total surface area of the droplets Polymerization of the monomer in solution undoubtedly takes place but does not contribute signi cantly, since the monomer concentration is low and propagating radicals would precipitate out of aqueous solution at very small (oligomeric) size The micelles act as a meeting place for the organic (oil-soluble) monomer and the water-soluble initiator The micelles are favored as the reaction site because of their high monomer concentration (similar to bulk monomer concentration) compared to the monomer in solution.



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Rewriting (4.3) as IZ10:)1 2 = 0, we see that it implies that any state 10:) which satisfies (4.1) must also satisfy (4.4) Zlo:) = O. So la) is a right eigenstate of a with eigenvalue 0:, that is,

As polymerization proceeds, the micelles grow by the addition of monomer from the aqueous solution whose concentration is replenished by dissolution of monomer from the monomer droplets A simpli ed schematic representation of an emulsion polymerization system is shown in Fig 4-1 The system consists of three types of particles: monomer droplets, inactive micelles in which.

0,10:) = 10:)0:





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polymerization is not occurring, and active micelles in which polymerization is occurring The latter are no longer considered as micelles but are referred to as polymer particles An emulsi er molecule is shown as to indicate one end ( ) is polar or ionic and the other end ( ) nonpolar Two mechanisms for particle nucleation (ie, formation of polymer particles) have been discussed The process described above, called micellar particle nucleation, occurs when radicals from the aqueous phase enter the micelles (The term heterogeneous particle nucleation has been proposed as an alternative to the term micellar particle nucleation) The radicals may be primary radicals or, much more likely, oligomeric radicals formed by solution polymerization with degrees of polymerization of $2 5 [De Bruyn et al, 2002; Dong and Sundberg, 2002].

(4.5)

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Homogeneous particle nucleation involves solution-polymerized oligomeric radicals becoming insoluble and precipitating onto themselves (or onto dead oligomer in solution) [Fitch et al, 1969; Hansen and Ugelstad, 1978] The precipitated species become stabilized by absorbing surfactant (from solution, monomer droplets, and micelles) and on subsequent absorption of monomer are the equivalent of polymer particles formed by micellar nucleation The relative extents of micellar and homogeneous necleation are expected to vary with the surfactant concentration and the solubility of monomer in water Micellar nucleation is the predominant nucleation process when the surfactant concentration is well above CMC For styrene and methyl methacrylate, more than 99% of particle nucleation occurs by micellar nucleation [Herrera-Ordonez and Olayo, 2000, 2001; Saldivar et al, 1998] Since MMA is much more water-soluble than styrene (16 vs 0.

1Recently. a remarkable experiment realized for the first time a quantum nondemolition photon measurement, where a photon was detected without being destroyed [467]. This experiment could, however. detect only a single photon.

07 g L 1 ), solubility in water is not important in determining the mechanism for nucleation well above CMC Whether this is the case for vinyl acetate and other monomers more water-soluble than MMA is unclear Around CMC, micellation nucleation is still the predominant mode of nucleation, but homogeneous nucleation is present more for vinyl acetate and methyl methacrylate and less for styrene The situation is much different for all monomers when the surfactant concentration is well below CMC Micelles are absent below CMC and only homogeneous nucleation occurs In fact, the occurrence of emulsion polymerization in the absence of micelles is evidence for the homogeneous nucleation mechanism It has been suggested that an important growth process for the rst-formed polymer particles, sometimes called precursor particles, is coagulation with other particles and not polymerization of monomer.

Notice that ahas no left eigenstates (see Problem 4.1), but it has right eigenstates, as can easily be demonstrated by finding the explicit solutions (see Problem 4.2) of (4.5). Physically, (4.5) means that the la} are states that are insensitive to the annihilation of a photon. This makes such states quasi classical because then a photodetection measurement does not disturb them. As condition (4.1) is also the condition for full coherence [235] (i.e., for having maximum fringe contrast in interference experiments), the states la} are called coherent states. Instead of calculating these coherent states directly from (4.5), as in Problem 4.2, we obtain them here in a more indirect way. This will pay dividends later, as one of the spin-offs of this indirect route will tum out to be a very useful tool. Consider the unitary operator D(a) [i.e., Dt(a)D(a) = i], which has the following effect on a: Dt (a)aD(a) = a + a. (4.6) Then the coherent state la} will be given by

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