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Control is achieved by limiting conversion to no more than 30% per pass The polymerization is effectively carried out as a solution or suspension process (with unreacted monomer acting as solvent or diluent) depending on whether the pressure is above or below 200 MPa Autoclave reactors differ from tubular reactors in two respects Autoclave reactors have much smaller length-to-diameter ratios (2 4 for single-zone and up to 15 18 for multizone reactors) and operate at a much narrower reaction temperature range The polyethylene produced by radical polymerization is referred to as low-density polyethylene (LDPE) or high-pressure polyethylene to distinguish it from the polyethylene synthesized using coordination catalysts (Sec 8-11b) The latter polyethylene is referred to as high-density polyethylene (HDPE) or low-pressure polyethylene Low-density polyethylene is more highly branched (both short and long branches) than high-density polyethylene and is therefore lower in crystallinity (40 60% vs 70 90%) and density (0.



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If you can find a command line converter, then you can execute the command line. Another option would be to open the document in word ...

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Word highlights the next edit in the document. Click the Accept button to add the change to the final document.

(3.109)





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91 093 g cm 3 vs 094 096 g cm 3 ) Low-density polyethylene has a wide range and combination of desirable properties Its very low Tg of about 120 C and moderately high crystallinity and Tm of 105 115 C give it exibility and utility over a wide temperature range It has a good combination of strength, exibility, impact resistance, and melt ow behavior The alkane nature of polyethylene imparts a very good combination of properties Polyethylene is highly resistant to water and many aqueous solutions even at high temperatures It has good solvent, chemical, and oxidation resistance, although it is slowly attacked by oxidizing agents and swollen by hydrocarbon and chlorinated solvents at room temperature Polyethylene is a very good electrical insulator Commercial low-density polyethylenes have number-average molecular weights in the range 20,000 100,000, with X w =X n in the range 3 20.

(3.110)

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A wide range of LDPE products are produced with different molecular weights, molecular-weight distributions, and extents of branching (which affects crystallinity, density, and strength properties), depending on the polymerization temperature, pressure (ie, ethylene concentration), and reactor type Long-chain branching increases with increasing temperature and conversion but decreases with increasing pressure Short-chain branching decreases with increasing temperature and.

into (3.42), we obtain the following equations in vector notation (see Problem 3.1)

conversion but increases with pressure Autoclave processes generally yield polyethylenes with narrower molecular weight distributions but increased long-chain branching compared to tubular processes The wide range and combination of properties, including the ease of fabrication by a variety of techniques, makes LDPE a large-volume polymer Over 8 billion pounds were produced in 2001 in the United States; worldwide production was more than 3 times that amount These amounts are especially signi cant when one realizes that commercial quantitites of polyethylene did not become available until after World War II in 1945 Polyethylene was discovered in the early 1930s at the ICI laboratories in England and played an important role in the outcome of World War II The combination of good electrical properties, mechanical strength, and processability made possible the development of radar, which was critical to turning back Germany s submarine threat and air attacks over England.

Film applications account for over 60% of polyethylene consumption Most of this is extrusion-blown lm for packaging and household uses (bags, pouches, and wrap for food, clothes, trash, and dry cleaning) and agricultural and construction applications (greenhouses, industrial tank and other liners, moisture and protective barriers) Injection molding of toys, housewares, paint-can lids, and containers accounts for another 10 15% About 5% of the LDPE produced is used as electrical wire and cable insulation (extrusion coating and jacketing) for power transmission and communication Extrusion coating of paper to produce milk, juice, and other food cartons and multiwall bags accounts for another 10% Other applications include blow-molded squeeze bottles for glue and personal-care products Trade names for polyethylene include Alathon, Alkathene, Fertene, Grex, Hostalen, Marlex, Nipolon, and Petrothene Low- and high-density polyethylene, polypropene, and polymers of other alkene (ole n) monomers constitute the polyole n family of polymers.

(3.111) (3.112) (3.113) (3.114)

All except LDPE are produced by coordination catalysts Coordination catalysts are also used to produce linear low-density polyethylene (LLDPE), which is essentially equivalent to LDPE in structure, properties, and applications (Sec 8-11c) The production gures given above for LDPE do not include LLDPE The production of LLDPE now exceeds that of LDPE, with about 10 billion pounds produced in 2001 in the United States (Copolymers constitute about one-quarter of all low density polyethylenes; see Sec 6-8b) 3-14b Polystyrene.

B = \l AA,

Continuous solution polymerization is the most important method for the commercial production of polystyrene although suspension polymerization is also used [Moore, 1989].

(3.115)

3-206

E == -\lcp - -;;7}t,

Note: To accept all changes in the document, click the Accept and choose Accept All Changes in Document.

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