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Sci, 14, 214 (1954) Walling, C, Free Radicals in Solution, Chaps 3 5, Wiley-Interscience, New York, 1957 Walling, C and L Heaton, J Am Chem Soc, 87, 38 (1965) Walling, C and G Metzger, J Am Chem Soc, 81, 5365 (1959) Wang, J-S and K Matyjaszewski, J Am Chem Soc 117, 5614 (1995a); Macromolecules, 28, 7572 (1995b) Wang, J-S, T Grimaud, and K Matyjaszewski, Macromolecules, 30, 6507 (1997) Weale, K E, The In uence of Pressure on Polymerization Reactions, Chap 6 in Reactivity, Mechanism and Structure in Polymer Chemistry, A D Jenkins and A Ledwith, eds, Wiley-Interscience, New York, 1974 Wieland, P C, B Raether, and O Nuyken, Macromol Rapid Commun, 22, 700 (2002) Wilson, J E, Radiation Chemistry of Monomers, Polymers and Plastics, Chaps 1 5, Marcel Dekker, New York, 1974 Winkler, R E, and E.



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+ /L2 S {~tik~ + /L 21ltik1l}.

B Nauman, J Polym Sci Polym Chem Ed, 26, 2857 (1988) Wolf, C and W Burchard, Makromol Chem, 177, 2519 (1976) Woodbrey, J C and P Ehrlich, J Am Chem Soc, 85, 1580 (1963) Worsfold, D J and S Bywater, J Polym Sci, 26, 299 (1957) Yaeger, W L and V J Castelli, Antifouling Applications of Various Tin-Containing Organometallic Polymers, pp 175 180 in Organometallic Polymers, C E Carraher, Jr and J E Sheats, eds, Academic Press, New York, 1978 Yamada, B, D G Westmoreland, S Kobatake, and O Konosu, Prog Polym Sci, 24, 565 (1999) Yamago, S, K Iida, and J-I Yosida, J Am Chem Soc, 124, 2874 (2002) Yamamoto, K and M Sugimoto, J Macromol Sci Chem, A13, 1067 (1979) Yamazoe, H, P B Zetterland, B Yamada, D J Hill, and P J Pomery, Macromol Chem.

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Then use Jk 2 + /L2~ = -K~ + /L 21l and Jk 2 + /L 21lt = 1ltK + ~t instead of Jk 2 + /L2~t = _~t K + /L21lt and Jk 2 + /L 21l = K1l + ~, and show that

Phys, 202, 824 (2001) Yassin, A A and N A Risk, Polymer, 19, 57 (1978a); J Polym Sci Polym Chem Ed, 16, 1475 (1978b) Yasuda, H, Plasma Polymerization, Academic Press, New York, 1986 Yasuda, M, H Seki, H Yokoyama, H Ogino, K Ishimi, and H Ishikawa, Macromolecules, 34, 3261 (2001) Yoshioka, M, A Matsumoto, and T Otsu, Polym J, 23, 1249 (1991) Yoshikawa, C, A Goto, and T Fukuda, Macromolecules, 35, 5801 (2002); 36, 908 (2003) Yousi, Z, L Jian, Z Rongchuan, Y Jianliang, D Lizong, and Z Lansun, Macromolecules, 33, 4745 (2000) Zahalka, H A, B Robillard, L Hughes, J Lusztyk, G W Burton, E G Janzen, Y Kotake, and K U Ingold, J Org Chem, 53, 3789 (1988) Zetterlund, P B, H Yamazoe, B Yamada, D J T Hill, and P J Pomery, Macromolecules, 34, 7686 (2001).

+ /L 21l) }

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Zhang, H, B Klumperman, and R van der Linde, Macromolecules, 35, 2261 (2002)..

2 3 - (27T)31i J d k ~ f.njk 2~S {~tik~ + /L 1ltIk1l} .

Zhang, H., B. Klumperman, W. Ming, H. Fischer, and R. van der Linde, Macromolecules, 34, 6169 (2001). Zutty, N. L. and R. D. Burkhart, Polymer Synthesis at High Pressures, Chap. 3 in Polymerization and Polycondensation Processes, N. A. J. Platzker, ed., American Chemical Society, Van Nostrand Reinhold, New York, 1962.

Now, proceeding in the same way as was done for the momentum, show that I n is given by (3.95). 3.5 Show that due to the transversality condition k 1/J = 0, it is impossible to make a linear combination of plane waves that leads to a delta function in configuration space. 43 Notice that for nonvanishing /L, such a linear combination is possible but it must contain antiparticles (i.e., negative frequencies) as well as particles (i.e., positive frequencies). 3.6 Show that (3.134) holds in two different ways:

PROBLEMS 3-1 When one considers the various polymers produced from carbon carbon double bond monomers, the following generalizations are apparent: a The polymers are produced almost exclusively from ethylene, monomers that have one substituent on the double bond, or monomers that have two substituents on the same carbon atom of the double bond Monomers containing one substituent on each carbon of the double bond seldom polymerize b Most of the chain polymerizations are carried out by radical initiation; relatively few are produced by ionic initiation Why Are there good reasons for these generalizations or are they simply a matter of chance Discuss 3-2 3-3 Show by chemical equations the polymerization of acrylonitrile initiated by the thermal decomposition of cumyl hydroperoxide Using 14C-labeled AIBN as an initiator, a sample of styrene is polymerized to an number-average degree of polymerization of 1:52 104 .

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