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An Unreliable Connectionless Service All of the Ethernet technologies provide connectionless service to the network layer That is to say, when adapter A wants to send a datagram to adapter B, adapter A encapsulates the datagram in an Ethernet frame and sends the frame into the LAN, without first "handshaking" with adapter B This layer-2 connectionless service is analogous to IP's layer-3 datagram service and UDP's layer-4 connectionless service All the Ethernet technologies provide an unreliable service to the network layer In particular when adapter B receives a frame from A, adapter B does not send an acknowledgment when a frame passes the CRC check (nor does it send a negative acknowledgment when a frame fails the CRC check) Adapter A hasn't the slightest idea whether a frame arrived correctly or incorrectly When a frame fails the CRC check, adapter B simply discards the frame This lack of reliable transport (at the link layer) helps to make Ethernet simple and cheap But it also means that the stream of datagrams passed to the network layer can have gaps If there are gaps due to discarded Ethernet frames, does the application-layer protocol at host B see gaps as well As we learned in 3, this solely depends on whether the application is using UDP or



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Spit re cockpit (Courtesy of Gordon G. Bartley)

This novel molecular sieve was synthesized by hydrothermal reactions of capatal alumina, tetramethylammonium silicate, and sodium silicate in the presence of ionic surfactants It opened a new era of mesoporous materials because of their high surface area (W700 m2 g 1), controllable pore size in a wide range (15 10 nm), and versatile pore surface chemistries Following this pioneering work, material scientists have synthesized mesoporous inorganic networks with different mesostructures (lamellar, two-dimensional (2-D) hexagonal, three-dimensional (3-D) hexagonal, face-centered cubic (FCC), body-centered cubic (BCC), and primitive cubic), using a wide range of surfactants including cationic surfactants (CTAB), anionic surfactants (SDS), nonionic surfactants (Brij 56), and amphiphilic block copolymers (P123), of interest in potential applications in catalysis, membrane separations, adsorption, and chemical sensing Evaporation-Induced Self-Assembly.

file:///D|/Downloads/Livros/computa o/Computer%20Net%20Approach%20Featuring%20the%20Internet/ethernethtm (4 of 12)20/11/2004 15:52:37





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The hydrothermal process designed for MCM-41 is time consuming, and more importantly, the mesoporous products are usually ill-de ned powders that are not transparent, precluding their general applications in thin lms and optical applications Brinker and colleagues developed a new technique denoted as evaporation-induced self-assembly (EISA) to improve the MCM-41 type materials for the fast formation of mesostructured nanoparticles (Lu et al, 1999) and thin lms (Lu et al, 1997) In the EISA process for lm formation during dip-coating, a substrate is dipped into a homogeneous solution of soluble silica, surfactant, water, and acid in ethanol solvent, with an initial surfactant concentration far below the critical micelle concentration (CMC), and withdrawn from the sol solution at a constant speed Preferential evaporation of ethanol concentrates the surfactant, water, acid, and silica species in the depositing lm.

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TCP If the application is using UDP, then the application-layer protocol in host B will indeed suffer from gaps in the data On the other hand, if the application is using TCP, then TCP in host B will not acknowledge the discarded data, causing TCP in host A to retransmit Note that when TCP retransmits data, Ethernet retransmits the data as well But we should keep in mind that Ethernet doesn't know that it is retransmitting Ethernet thinks it is receiving a brand new datagram with brand new data, even though this datagram contains data that has already been transmitted at least once Baseband Transmission and Manchester Encoding Ethernet uses baseband transmission, that is, the adapter sends a digital signal directly into the broadcast channel The interface card does not shift the signal into another frequency band, as do ADSL and cable modem systems Ethernet also uses Manchester encoding, as shown in Figure 55-3 With Manchester encoding each bit contains a transition; a 1 has a transition from up to down, whereas a zero has a transition from down to up The reason for Manchester encoding is that the clocks in the sending and receiving adapters are not perfectly synchronized By including a transition in the middle of each bit, the receiving host can synchronize its clock to that of the sending host Once the receiving adapter's clock is synchronized, the receiver can delineate each bit and determine whether it is a one or zero Manchester encoding is a physical layer operation rather than a link-layer operation; however, we have briefly described it here as it is used extensively in Ethernet

Nodes in an Ethernet LAN are interconnected by a broadcast channel, so that when an adapter transmits a frame, all the adapters on the LAN receive the frame As we discussed in section 53, Ethernet uses a CSMA/CD multiple access algorithm Summarizing our discussion from Section 53, recall that CSMA/ CD employs the following mechanisms:

Further evaporation of ethanol concentrates the surfactant to exceed CMC and causes the formation of micelles Beyond this point, progressively increasing surfactant concentration drives self-assembly of silica-surfactant micelles and their organization into highly ordered liquid crystalline mesophases (cubic, hexagonal, or lamellar) that depend on the.

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