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7), the various isomerization combinations (EEE, EEZ, EZZ, and ZZZ) could all be separated by thin-layer chromatography because of their different physical properties (Junge and McGrath, 1999) The conformational change associated with isomerization modi es (typically reduces) the hydrodynamic volume, with the speci c extent of conformational change depending strongly on where the azo units are incorporated (Li and McGrath, 2000) 1134 Polyelectrolyte Multilayers A new facile and versatile lm preparation technique, layer-by-layer electrostatic self-assembly, has become the subject of intensive research since its introduction by Decher (Decher, 1997; Decher and Schmitt, 1992; Decher and Hong, 1991; Decher et al, 1991) In this technique, a charged or hydrophilic substrate is immersed in a solution of charged polymers (polyelectrolytes), which adsorb irreversibly onto the substrate.



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After rinsing, the substrate is then immersed in a solution containing a polyelectrolyte of opposite charge, which adsorbs electrostatically to the charged polymer monolayer Because each layer of adsorbed polymer reverses the surface charge, one can build up an arbitrary number of alternating polycation polyanion layers These polyelectrolyte multilayers (PEMs) are easy to prepare, use benign (all-aqueous) chemistry, and are inherently tunable (Decher et al, 1998; Hammond, 1999; Knoll, 1996) Speci cally, by adjusting the ionic strength (Steitz et al, 2000; Linford et al, 1998; Losche et al, 1998; Sukhorukov et al, 1996) or pH (Burke and Barrett, 2003a; Chung and Rubner, 2002; Wang et al, 2002; Shiratori and.





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Secrecy Only the sender and intended receiver should be able to understand the contents of the transmitted message Because eavesdroppers may intercept the message, this necessarily requires that the message be somehow encrypted (disguise data) so that an intercepted message can not be decrypted (understood) by an interceptor This aspect of secrecy is probably the most commonly perceived meaning of the term "secure communication" Note, however, that this is not only a restricted definition of secure communication (we list additional aspects of secure communication below), but a rather restricted definition of secrecy as well For example, Alice might also want the mere fact that she is communicating with Bob (or the timing or frequency of her communications) to be a secret! We will study cryptographic techniques for encrypting and decrypting data in section 72 Authentication Both the sender and receiver need to confirm the identity of other party involved in the communication - to confirm that the other party is indeed who or what they claim to be Face-to-face human communication solves this problem easily by visual recognition When communicating entities exchange messages over a medium where they can not "see" the other party, authentication is not so simple Why, for instance, should you believe that a received email containing a text string saying that the email came from a friend of yours indeed came from that friend If someone calls on the phone claiming to be your bank and asking for your account number, secret PIN, and account balances for verification purposes, would you give that information out over the phone Hopefully not We will examine authentication techniques in section 73, including several that, perhaps surprisingly, also rely on the cryptographic techniques we study in section 72 Message Integrity Even if the sender and receiver are able to authenticate each other, they also want to insure.

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100 Time (min)

file:///D|/Downloads/Livros/computa o/Computer%20Netwopproach%20Featuring%20the%20Internet/security_introhtm (1 of 4)20/11/2004 15:53:00

Figure 9.35 V-22 rotor and wing stowage sequence (Courtesy of Boeing/Bell)

Figure 3.4. Swelling behavior of slide-ring gels in DMSO upon alternate irradiation of UV and visible light. D and D0 are diameters of the gel and inner diameter of mold capillary, respectively. Source: Sakai et al., 2007.

that the content of their communication is not altered, either malicously or by accident, in transmission Extensions to the checksumming techniques that we encountered in reliable transport and data link protocols will also be studied in section 73; these techniques also rely on cryptographic concepts in section 72 Having established what we mean by secure communication, let us next consider exactly what is meant by an "insecure channel" What information does an intruder have access to, and what actions can be taken on the transmitted data Figure 71-1 illustrates the scenario

Figure 71-1: Sender, receiver and intruder (Alice, Bob, and Trudy)

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