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As we learned in 4, routers are store-and-forward packet switches that forward packets using IP addresses Although a bridge is also a store-and-forward packet switch, it is fundamentally different from a router in that it forwards packets using LAN addresses Whereas a router is layer-3 packet switch, a bridge is a layer-2 packet switch



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Z Naturforsch, A: Phys Sci 36(11):1180 1186 Rau H, Greiner G, Gauglitz G, Meier H 1990 Photochemical quantum yields in the A B system when only the spectrum of A is known J Phys Chem 94(17):6523 6524 Razna J, Hodge P, West D, Kucharski S 1999 NLO properties of polymeric Langmuir Blodgett lms of sulfonamide substituted azobenzenes J Mater Chem 9(8):1693 1698 Reynier N, Dozol J F, Saadioui M, Asfari Z, Vicens J 1998 Complexation properties of a new photosensitive calix[4]arene crown ether containing azo unit in the lower rim towards alkali cations Tetrahedron Lett 39(36):6461 6464 Richert L, et al 2002 Cell interactions with polyelectrolyte multilayer lms Biomacro molecules 3(6):1170 1178 Rmaile HH, Schlenoff JB 2003 Optically active polyelectrolyte multilayers as membranes for chiral separations J Am Chem Soc 125(22):6602 6603 Rochon P, Batalla E, Natansohn A 1995 Optically induced surface gratings on azoaro matic polymer lms.





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file:///D|/Downloads/Livros/computa o/Computer%20Netwoch%20Featuring%20the%20Internet/transparent_bridgeshtm (6 of 12)20/11/2004 15:52:39

Even though bridges and routers are fundamentally different, network administrators must often choose between them when installing an interconnection device For example, for the network in Figure 56-2, the network administrator could have just as easily used a router instead of a bridge Indeed, a router would have also kept the three collision domains separate while permitting interdepartmental communication Given that both bridges and routers are candidates for interconnection devices, what are the pros and cons of the two approaches

Appl Phys Lett 66(2):136 138 Rottger D, Rau H 1996 Photochemistry of azobenzenophanes with three membered bridges J Photochem Photobiol A Chem 101(2 3):205 214 Rouse JH, Ferguson GS 2002 Stepwise incorporation of nonpolar polymers within polyelectrolyte multilayers Langmuir 18(20):7635 7640..

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To operate the seat the pilot pulls on a handle between the thighs. This causes the canopy to be ejected or shattered and the pilot s legs and arms are restrained into the seat to stop the limbs ailing. A ballistic gas generator then ejects the seat up a pair of guide rails and out of the aircraft. At separation a rocket motor res to continue the trajectory over the n. After ejection a stabilising drogue parachute is activated, the seat is separated from the pilot and a main parachute deploys. This process is controlled by an onboard multi-mode electronic sequencer and backed up by a barostatic pressure sensor. The Mk 16 seat used on the Euro ghter Typhoon utilises a second-generation digital seat sequencer which continuously senses external environmental

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50 mM KCl in a cubic cell. Fig. 13.12c shows the UV/visible spectra data of a Brij 56 templated TSUA-modi ed, nanocomposite lm coated on an ITO/glass substrate. The lm exhibits an excellent reversible photoisomerization phenomenon. UV irradiation causes gradual decreases in the p p* transition band (355 nm) and increases in the n p* transition band (456 nm). The reverse cistrans isomerization can be achieved by a visible light exposure (l = 435 nm). A comparison between the absorbance in air (Fig. 13.12a) and absorbance in buffer solution (Fig. 13.12c) shows the aqueous environment causing a decrease in the absorbance in the n p* transition band. This indicates weaker hydrogen-bonding interactions between the azo and silanol groups on the silica wall than those present in air. Brinker and coworkers also monitored the absorbance (A) at 355 nm (p p* transition) in situ to calculate the kinetics of the cis-trans isomerization of the azobenzene ligands contained in the nanocomposite lm deposited on the ITO/ glass substrate in buffer solution (Liu, 2004). The rst-order plot of ln((AN A0)/ (AN At)) vs. t was not perfectly linear in the entire region. The slope (rate constant, k) gradually decreases (to250 min) and remains constant (tW250 min). The deviation from rst-order kinetics is common for azobenzene ligands con ned in sol gel matrices or polymers (Bohm et al., 1996; Ueda et al., 1992). These data imply that the kinetics is composed of two parts, a fast one (k1) and a slow one (k2). When t is small, the fast process is predominant. On the contrary, the slow process becomes predominant as time (t) increases. A double exponential equation was used to t the data and evaluate k1 and k2. A t A 1 a1 e

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