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supramolecular helix at will, by changing the incident light handedness. There are many other examples of photocontrol of supramolecular order. The pitch of a cholesteric LC can be modi ed by isomerization (Sackmann, 1971). Biomacromolecular variants abound (Willner and Rubin, 1996). Azo-modi ed polypeptides can be photoswitched between ordered states (a-helix or b-sheet) and a random coil (Everlof and Jaycox, 2000; Fissi et al., 1996; Yamamoto and Nishida, 1991). The duplex of modi ed DNA can be reversibly switched (Asanuma et al., 2001), and the catalytic activity of histidine can be controlled (Lee and Ueno, 2001). Photoisomerization can also affect self-assembly behavior at the domain level. On irradiation, one can induce a phase change (Aoki et al., 2000), a solubility change (Arai and Kawabata, 1995; Yamamoto et al., 1990), crystallization (Ebralidze and Mumladze, 1990), or even reversal of phase separation (Ef ng and Kwak, 1995). The critical micelle concentration (cmc) and surface activity can also be modi ed (Yang et al., 1995). In an amphiphilic polypeptide system, selfassembled micelles were formed in the dark and could be disaggregated with light (Higuchi et al., 1994). When allowed to assemble as a transmembrane structure, the aggregate could be reversibly formed and destroyed using light, which allowed for reversible photoswitching of ion transport (Higuchi et al., 1995a). Related experiments on methacrylates (Chen et al., 1997a; Angiolini et al., 1995) and polypeptides (Sisido et al., 1991b) showed that a polymer s chiral helix could be reversibly suppressed on irradiation. In a series of polyisocyanate polymers, it could be selected whether irradiation would suppress or increase chirality (Muller and Zentel, 1996; Maxein and Zentel, 1995).



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Figure 59-1 shows such an ATM backbone with four entry/exit points for Internet IP taffic Note that each entry/exit point is a router An ATM backbone can span an entire continent and may have tens or even hundreds of ATM switches Most ATM backbones have a permanent virtual channel (VC) between each pair of entry/exit points (Recall that ATM uses the jargon "virtual channel" for "virtual circuit") By using permanent VCs, ATM cells are routed from entry point to exit point without having to dynamiccally establish and tear-down VCs Permanent VCs, however, are only feasible when the number of entry/exit points is relatively small For n entry points, n(n-1) permanent VCs are necessary Each router interface that connects to the ATM network will have two addresses The router interface will have an IP address, as usual And the router will have an ATM address, which is esssentially a LAN address (see Section 54





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(Deff,dark) and under UV irradiation (Deff,UV) were estimated to be 9.5 10 17 m2 s 1 and 1.7 10 16 m2 s 1, respectively. These values are much smaller than the effective diffusivity of FDM in Brij 56 templated photoresponsive nanocomposite membranes (Deff,dark = 1.1 10 14 m2 s 1, Deff,UV = 1.6 10 14 m2 s 1). As the pore size and probing molecule size are comparable in the two cases, the pore accessibility plays a major role. It was demonstrated that the photoresponsive nanocomposite membrane had a BCC mesostructure whereas the photoresponsive nanocomposite particles had an onionlike lamellar structure. Only the defects located on the particle surfaces could provide the pathway for uptake and release of OBN probe molecules, which lowered the effective diffusivity considerably.

file:///D|/Downloads/Livros/computa o/Computer%20NetDown%20Approach%20Featuring%20the%20Internet/atmhtml (1 of 10)20/11/2004 15:52:43

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Most likely this is caused by a missing font or CIDFont, the rectangles are the . notdef glyph which is used when a glyph cannot be found.

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Although vapour cycle systems are very ef cient, with a coef cient of performance typically ve times that of a comparable closed loop air cycle system, applications are limited due to problems such as their limited temperature range and heavy weight compared to air cycle systems. The maximum operating temperatures of many refrigerants are too low, typically between 65 C and 70 C, signi cantly less than the temperatures which are required for worldwide operation. It should be noted that chloro uorocarbons (CFC) endanger the ozone layer and are the subject of much debate calling for a limitation in their use.

Figure 59-1: ATM network in the core of an Internet backbone Consider now an IP datagram that is to be moved across the backbone in Figure 59-1 Let us refer to the router at which the datagram enters the ATM network as the "entry router" and the router at which the datagram leaves the network as the "exit router" The entry router does the following: 1 Examines the destination address of the datagram 2 Indexes its routing table and determines the IP address of the exit router (ie, the next router in its route) 3 To get the datagram to the exit router, the entry router views ATM as just another link-layer protocol In particular, the entry router indexes an ATM ARP table with the IP address of the exit router and determines the ATM address of the exit router 4 IP in the entry router then passes down to the link layer (ie, ATM) the datagram along with the ATM address of the exit router After these four steps have been completed, the job of moving the datagram to the exit router is out of the hands of IP and in the hands of ATM ATM must now move the datagram to the ATM destination address obtained in Step 3 above This task has two sub-tasks:

13.3.5. Reversible Photoswitching Liquid-Adsorption of Azobenzene-Modi ed Mesoporous Silica Materials

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