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Figure 59-2: The two sublayers of the physical layer, and their responsibilities The Physical Medium Dependent Sublayer The PMD sublayer is at the very bottom of ATM protocol stack As the name implies, the PMD sublayer depends on the physical medium of the link; in particularly, the sublayer is specified differently for different physical media (fiber, copper, etc) As shown in the above chart, it specifies the medium itself It is also responsible for generating and delineating bits There are two classes of PMD sublayers: PMD sublayers which have a transmission frame structure (eg, T1, T3, SONET, or SDH) and PMD sublayers which do not have a transmission frame structure If the PMD has a frame structure, then it is responsible for generating and delineating frames (The terminology "frames" in this section is not to be confused with link-layer frames used in the earlier sections of this The transmission frame is a



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(Fig. 13.21), an indication that the cis form azobenzene adsorbed less OBPc than the trans form azobenzene. The nearly constant OBPc concentration of each solution after repeated UV and visible light irradiation indicates that the change in the adsorption is reversible and reproducible. Fig. 13.21 shows the adsorption isotherms with clear difference in the adsorption amount of OBPc between the two forms (the trans form adsorbs more OBPc than the cis form). The head alkyl group affects adsorption amount of OBPc. Longer alkyl chain results in lower adsorption. A signi cant difference in adsorption between the trans form and the cis form was reported. A maximum value of 4.2 mg g 1 was observed when the alkyl group had four carbons, and a minimum value of 0.1 mg g 1 was measured when there was no alkyl head group. These results con ict with the nanovalve molecular gate mechanism (Liu et al., 2004), which suggests that the cis form should have a higher OBPc adsorption amount than the trans form. Maeda proposed a mechanism to explain the results. As in the case of the command surface on a at surface, the direction of the head alkyl groups control the orientation of the OBPc molecules adsorbed on the channel surfaces through the van der Waals interaction between the butoxy groups and the alkyl groups of azobenzene. When the azobenzene groups are in cis form, the OBPc molecules adsorbed on the pore surfaces are more randomly





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A typical liquid loop consists of an air/liquid heat exchanger which is used to dump the heat load being carried by the liquid into the air conditioning system, a pump and a reservoir as illustrated in Figure 7.17.

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physcial-layer mechanism for organizing the bits sent on a link) The PMD sublayer does not recognize cells Some possible PMD sublayers include: 1 SONET/SDH (Synchronous Optical Network / Synchronous Digital Hierarchy) over single-mode fiber Like T1 and T3, SONET and SDH have frame structures which establish bit synchronization between the transmitter and receiver at the two ends of the link There are several standardized rates, including: r OC-1: 5184 Mbps r OC-3: 15552 Mbps r OC-12: 62208 Mbps 2 T1/T3 frames over fiber, microwave, and copper 3 Cell based with no frames In this case, the clock at receiver is derived from transmitted signal Transmission Convergence Sublayer The ATM layer is specified independently of the physical layer; it has no concept of SONET, T1, or physical media A sublayer is therefore needed (1) at the sending side of the link to accept ATM cells from the ATM layer and put the cells' bits on the physical medium, and (2) at the receiving side of the link to group bits arriving from the physcial medium into cells and pass the cells to the ATM layer These are the jobs of the TC sublayer, which sits on top of the PMD sublayer and just below the ATM layer We note that the TC sublayer is also physical medium dependent -- if we change the physical medium or the underlying frame structure, then we must also change the TC sublayer On the transmit side, the TC sublayer places ATM cells into the bit and transmission frame structure of the PMD sublayer On the receive side, it extracts ATM cells from the bit and transmission frame structure of the PMD sublayer It also peforms header error correction (HEC) More specifically, the TC sublayer has the following tasks:

Figure 13.21. Variation in concentration of unadsorbed OBPc solution under UV and visible light irradiation. Source: From Maeda et al., 2006. Reprinted with permission.

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