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In a multi-tier design, we refer to the entire interconnected network as a LAN, and we refer to each of the departmental portions of the LAN (ie, the departmental hub and the hosts that connect to the hub) as a LAN segment It is important to note that all of the LAN segments in Figure 5-61 belong to the same collision domain, that is, whenever two or more nodes on the LAN segments transmit at the same time, there will be a collision and all of the transmitting nodes will enter exponential backoff Interconnecting departmental LANs with a backbone hub has many benefits First and foremost, it provides interdepartmental communication to the hosts in the various departments Second, it extends the maximum distance between any pair of nodes on the LAN For example, with 10BaseT the maximum distance between a node and its hub is 100 meters; therefore, in a single LAN segment the maximum distance between any pair of nodes is 200 meters By interconnecting the hubs, this maximum distance can be extended, since the distance between directly-connected hubs can also be 100 meters when using twisted pair (and more when using fiber) Third, the multi-tier design provides a degree of graceful degradation Specifically, if any one of the departmental hubs starts to malfunction, the backbone hub can detect the problem and disconnect the departmental hub from the LAN; in this manner, the remaining departments can continue to operate and communicate while the faulty departmental hub gets repaired Although a backbone hub is a useful interconnection device, it has three serious limitations that hinder its deployment First, and perhaps more important, when departmental LANs are interconnected with a hub (or a repeater), then the independent collision domains of the departments are transformed into one large and common collision domain Let us explore this latter issue in the context of Figure 56-1 Before interconnecting the three departments, each departmental LAN had a maximum throughput of 10 Mbps, so that maximum aggregate throughput of the three LANs was 30 Mbps But once the three LANs are interconnected with a hub, all of the hosts in the three departments belong to the same collision domain, and the maximum aggregate throughput is reduced to 10 Mbps A second limitation is that if the various departments use different Ethernet technologies, then it may not be possible to interconnect the departmental hubs with a backbone hub For example, if some departments use 10BaseT and the remaining departments use 100BaseT, then it is impossible to interconnect all the departments without some frame buffering at the interconnection point; since hubs are essentially repeaters and do not buffer frames, they cannot interconnect LAN segments operating at different rates A third limitation is that each of the Ethernet technologies (10Base2, 10BaseT, 100BaseT, etc) has restrictions on the maximum number of nodes that can be in a collision domain, the maximum distance between two hosts in a collision domain, and the maximum number of tiers that can be present in a multi-tier design These restrictions constrain both the total number of hosts that connect to a multi-tier LAN as well as geographical reach of the multi-tier LAN.



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By altering the electron density, the substitution pattern necessarily affects the dipole moment, and in fact all the higher order multipole moments This becomes signi cant in many nonlinear optical (NLO) studies For instance, the chromophore s dipole moment can be used to orient with an applied electric eld (poling), and the higher order moments of course de ne the molecule s nonlinear response (Delaire and Nakatani, 2000) In particular, the strongly asymmetric distribution of the delocalized electrons that results from push pull substitution results in an excellent NLO chromophore..





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In contrast to hubs, which are physical-level devices, bridges operate on Ethernet frames and thus are layer-2 devices In fact, bridges are full-fledged packet switches that forward and filter frames using the LAN destination addresses When a frame comes into a bridge interface, the bridge does not just copy the frame onto all of the other interfaces Instead, the bridge examines the destination address of the frame and attempts to forward the frame on the interface that leads to the destination Figure 56-2 shows how the three academic departments of our previous example might be interconnected with a bridge The three numbers next to the bridge are the interface numbers for the three bridge interfaces When the

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Key to some of the most intriguing results and interesting applications of azobenzenes is the facile and reversible photoisomerization about the azo bond, converting between the trans (E ) and cis (Z) geometric isomers (Fig. 1.3). This photoisomerization is completely reversible and free from side reactions, prompting Rau to characterize it as one of the cleanest photoreactions known. (Rau, 1990) The trans isomer is more stable by B50 kJ mol 1 (Mita et al., 1989; Schulze et al., 1977), and the energy barrier to the photoexcited state (barrier to isomerization) is on the order of 200 kJ mol 1 (Monti et al., 1982). Thus, in the dark, most azobenzene molecules will be found in the trans form. On absorption of a photon (with a wavelength in the trans absorption band), the azobenzene will convert, with high ef ciency, into the cis isomer. A second wavelength of light (corresponding to the cis absorption band) can cause the back-conversion.

file:///D|/Downloads/Livros/computa o/Computer%20Netwoch%20Featuring%20the%20Internet/transparent_bridgeshtm (2 of 12)20/11/2004 15:52:39

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