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In previous chapters, we introduced the ( three-tier model for building e-commerce applications. As an introduction to server-side programming, let us revisit the threetier model before discussing various server-side programming techniques. To achieve the purposes of modular design and platform independence, web-based e-commerce applications are usually developed based on the three-tier model as shown in Figure 4.1. By means of the three-tier model, we can separate the business logic of the web applications from the ccfrontendy web client) and (Le. the backend (i.e. database systems). This gives us a more flexible and scaleable system. In summary, the three-tier model has the following components: 1. The first tier W e b client: The first tier provides a web-based Graphical User Interface (GUI) displayed through a web browser in the client computer. Implementation of the web client in the web application is usually referred to as Web publishing and Client-side programming, which has been extensively discussed in 3. 2 . The second tier - Server-side application (SSA): The second tier consists of server-side applications that run on a web server or a dedicated application server. In general, these applications implement the business logic of the web system. In this chapter, we will give an overview of the following server-side programming techniques: Common Gateway Interface (CGI) Active Server Page (ASP) * Java Servlets We will compare their advantages and shortcomings. As an example, we will use Java Servlets as the server-side programming tool throughout the book.



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can contain hundred, or even thousands of rules, some of them quite complex. To give you a avor of a more sophisticated rule, here is one from the aforementioned MYCIN, an expert system that was designed to determine the cause of a bacterial infection:

6. Enter the address to the Subversion server in the Server Address field, without the protocol. For example, idest.myversioncontrol.com instead of https://idest .myversioncontrol.com. 7. Enter the path to your repository in the Repository Path field.

e x(cos y i sin y) e x(cos y i sin y) e z . Answer: All z. ivx u iv, hence ux u, vx v. By integration, u c1(y)e x, v c2(y)e x.





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are especially important in UNCD lms where a signi cant density of mid-gap states is expected at the grain boundaries Furthermore, the position of the bands and mid-gap states at the surface is largely determined by the surface electron af nity, which is negative for H-terminated surfaces ( 13 eV) and positive for O-terminated surfaces (+17 eV) Figure 169 illustrates a possible scenario to explain the spontaneous grafting of diazonium salts to H- and O-terminated ultrananocrystalline diamond surfaces The position of the LUMO level of the diazonium aromatic ion lies at about 44 eV below the vacuum level In the case of H-terminated surfaces, both valence band and mid-gap states are able to provide electrons to the LUMO level On the other hand, in the case of O-terminated UNCD only electrons from mid-gap states are able to reduce the diazonium salt.

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Thus, the different surface coverage observed for H- and O-terminated UNCD surfaces could be explained by the different reducing capacities of these two surfaces, which arise from their different electron af nities 16324 Chemical modi cation of O-terminated diamond surfaces Several groups have investigated the chemical modi cation of O-terminated diamond surfaces [48, 49] In contrast to H-terminated surfaces, an important chemical heterogeneity is expected at oxidized diamond surfaces Indeed, it is well known that several oxygen-related surface groups (the most important are ether, carbonyl, and hydroxyl groups) are present at oxidized surfaces, whose chemical composition depends on the crystal orientation as well as on the oxidation process [26, 50] Among these available groups, hydroxyls are very attractive because of their good reactivity; for example, the well-established alkoxysilane chemistry is based on the reaction with hydroxyl groups.

An extensive review on the use of alkoxysilane chemistry for surface functionalization can be found elsewhere [51] Figure 1610 schematically summarizes the attachment of silanes to a hydroxylterminated diamond surface: the silane molecules, here 3-aminopropyl diethoxymethylsilane (APDEMS) dissolved in toluene, react with silanols in the water layer present on the hydrophilic diamond surface These silanols immediately form covalent bonds to deprotonate hydroxyl groups at the surface, or can react with silanols of nearby molecules to form siloxane networks The presence of hydroxyl groups on the hydrophilic surface is thus an essential requirement for the silanization process [52] As mentioned above, the presence of hydroxyl groups at oxidized diamond surfaces depends on the crystal orientation and on the oxidation process used Thus, UNCD surfaces, with randomly oriented, nanoscaled, diamond grains, are suitable substrates to investigate this grafting mechanism..

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