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Suddenly throwing such a massive amount of capital at a relatively stable asset base caused prices to skyrocket, which led to a selfreinforcing cycle: In order to afford a home, prospective homeowners had to borrow more and take on risky, exotic mortgages instead of conservative 30-year, xed-rate, fully amortizing mortgages In turn, exotic mortgages and loose lending terms allowed homeowners to borrow much more money, thereby driving prices ever higher The bubble manifested itself in different ways in different parts of the country As discussed later, in inner cities like Detroit, equitystripping schemes were common; in Florida, Arizona, and Nevada, there was widespread speculation and overbuilding; and in California, which has 10 percent of the nation s homes but is where 34 percent of the foreclosures are happening (44 percent by dollar value), the bubble was primarily an affordability problem.



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That s not to say there wasn t equity stripping in California s inner cities nor an affordability problem in Florida, but these are the general characterizations Figure 14 shows what happened to housing affordability in three cities in southern California: Los Angeles, Riverside, and San Diego One can see that the percentage of households that could afford the average home in these three cities, as measured by the National Association of Home Builders (NAHB)/Wells Fargo Housing Opportunity Index, plunged as this decade progressed, to the point that fewer than 10 percent of households could afford the average home using a standard mortgage..

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10 At these levels, ACM s supposedly market neutral portfolios had effective durations of about three times the magnitude of the US Treasury market The trustee s report concludes: Whether knowingly, recklessly or negligently on ACM s part, the Granite Fund portfolios were badly out of tilt,.

functionalization of O-terminated surfaces So far, three different approaches have been generally used to functionalize H-terminated diamond surfaces: photochemical, electrochemical, and chemical methods For O-terminated surfaces, only chemical methods have been reported Because of its relevance, the functionalization of H-terminated diamond surfaces is discussed rst, followed by the functionalization of O-terminated surfaces 16321 Photochemical modi cation of H-terminated diamond surfaces Hamers and coworkers have pioneered the photochemical functionalization of H-terminated diamond surfaces [4, 36] The process is based on the reactivity of alkene molecules with a terminal double bond towards H-terminated diamond surfaces upon illumination with UV-light, as shown diagrammatically in Figure 163 A detailed explanation of the experimental details can be found in the references [4, 36] In short, the H-terminated diamond surface is covered with a solution containing the desired alkene molecules, and illuminated with UV light (normally 254 nm) for several hours.

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Using careful X-ray photoelectron spectroscopy characterization, the Hamers group has reported monolayer surface coverage after approximately 10 hours of illumination [37] The grafting process is thought to occur in the following steps: (i) electron injection from the diamond surfaces into the liquid phase, (ii) formation of reactive species such as radicals, and (iii) surface reaction The exact origin of the ejected electrons is still under debate Nichols et al suggested that electrons from defect states are photoexcited into the conduction band and, due to the negative electron af nity of H-terminated diamond surfaces, can be ejected to the liquid phase [38] Shin et al, on the other hand, suggested that electrons are directly excited from the valence band of diamond into the molecular acceptor level of the alkene molecule [39].

In both cases, the negative electron af nity of diamond plays an important role, which explains the experimentally observed, strong speci city of this grafting mechanism for H-terminated surfaces 16322 Electrochemical modi cation of H-terminated diamond surfaces Swain and coworkers reported for the rst time on the covalent grafting of aromatic groups to diamond surfaces by the electrochemical reduction of phenyl diazonium salts in.

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