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low-amplitude, higher-order components, and can therefore be expected to perform well in circular arrays over large bandwidths. The similarity between the two in the nontransformed domain (that is, as a function of the azimuth angle) is demonstrated in Figure 2.15. The derivation of the slot pattern is presented in 6. The (cos ) case is similar to a microstrip patch H-plane pattern. The transfer function from excitation mode to radiation mode, mode stability [Davies 1983], is demonstrated in Figure 2.16 for several element types and mode orders. The spectra in Figure 2.14, including the first 10 components were used. For isotropic elements, the mode stability is given directly by the Bessel function (Equation 2.25), whereas the general case is given by Equation (2.34). We see that all directional elements show promise for broadband performance. The case with m = 5 illustrates also that effective radiation requires the array to be big enough in order to avoid superdirectivity (kR = Nd/ < 4; one could, e.g., use 10 elements and d/ < 0.4).





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Remember, custom menu sets are not accessible in Layout mode, so you must be in Browse, Find, or Preview mode to switch custom menu sets.

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Evidence also suggests, however, that alkanes with only five carbon atoms in a linear chain may undergo aromatization via 1,5 ring closure followed by ring enlargement. Numerous mechanisms were put forward to rationalize these transformations 09 Dual-function catalysts possessing both metallic and acidic sites bring about more complex transformations. Carbocationic cyclization and isomerization as well as reactions characteristic of metals occurring in parallel or in subsequent steps offer new reaction pathways. Alternative reactions may result in the formation of the same products in various multistep pathways. Mechanical mixtures of acidic supports (silica-alumina) and platinum gave results similar to those of platinum supported on acidic alumina 14,21S This indicates that proximity of the active sites is not a requirement for bifunctional catalysis, that is, that the two different functions seem to operate independently. In the dehydrocyclization of alkanes it is clear that ring closure can take place both in a metal-catalyzed reaction and as a carbocationic process. The interpretation of the reforming process proposed by Heinemann and coworkers,123 therefore, is not a complete picture of the chemistry taking place. The scheme they presented (Fig. 2.1) attributes cyclization activity solely to acidic sites. The ample evidence available since requires that metal-catalyzed Cs and C6 ring-closure possibilities be included in a comprehensive interpretation. Additionally, the metal component plays and important role in carbocationic reactions in that it generates carbocations through the formation of alkenes. Alkylaromatic compounds possessing a sufficiently long side chain may also undergo dehydrocyclization 16 In fact, the aromatic ring enhances this reaction; alkylaromatics undergo dehydrocyclization faster than do alkanes. Depending on the side chain, condensed or isolated ring systems may be formed. Platinum, the most studied metal, catalyzes both Cs and C6 cyclizations in parallel reactions. n-Butylbenzene, for example, gives methylindan and methylindenes,

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