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Microsuspension polymerizations are suspension polymerizations in which the size of monomer droplets is about 1 mm Dispersion polymerization involves an initially homogeneous system of monomer, organic solvent, initiator, and particle stabilizer (usually uncharged polymers such as poly(N-vinylpyrrolidinone) and hydroxypropyl cellulose) The system becomes heterogeneous on polymerization because the polymer is insoluble in the solvent Polymer particles are stabilized by adsorption of the particle stabilizer [Yasuda et al, 2001] Polymerization proceeds in the polymer particles as they absorb monomer from the continuous phase Dispersion polymerization usually yields polymer particles with sizes in between those obtained by emulsion and suspension polymerizations about 1 10 mm in diameter For the larger particle sizes, the reaction characteristics are the same as in suspension polymerization For the smallest particle sizes, suspension polymerization may exhibit the compartmentalized kinetics of emulsion polymerization..



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If you are having trouble finding just the right word or phrase, you can use Word s thesaurus to find synonyms. Select the word for which you want to find a synonym. Click the Review tab. Click the Thesaurus button. Position your mouse pointer over the word you want to use as a replacement. Click the and click Insert.

Monomer disappears by the initiation reaction (Eq. 3-14) as well as by the propagation reactions (Eq. 3-15). The rate of monomer disappearance, which is synonymous with the rate of polymerization, is given by

34We will see later that this interpretation holds in a course-grained way [119, 311, 428J. It also holds in the paraxial approximation [151J.

d M Ri Rp dt 3-20





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is like a pocket-map that for use must be unfolded." Before going back to the more familiar vector notation, it is useful to find out which of the vectors in F and A are polar and which are axial. A polar vector remains the same when we change from a right-handed coordinate system to a left-handed one. An axial vector reverses its direction (i.e., goes into minus itself) under such a change of coordinates. To go from our right-handed coordinate system to a left-handed one, we can change Xl into -Xl. Let us denote the new coordinates and all quantities in the new coordinate system in general by adding a prime to their old names. The chainrule tells us that the partial derivatives in the new coordinates relate to those in the old ones by

where Ri and Rp are the rates of initiation and propagation, respectively. However, the number of monomer molecules reacting in the initiation step is far less than the number in the propagation step for a process producing high polymer. To a very close approximation the former can be neglected and the polymerization rate is given simply by the rate of propagation

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d M Rp dt 3-21

ax~ = -

The rate of propagation, and therefore the rate of polymerization, is the sum of many individual propagation steps. Since the rate constants for all the propagation steps are the same, one can express the polymerization rate by

aXI'

Rp kp M M 3-22

- aX2'

where [M] is the monomer concentration and [M ] is the total concentration of all chain radicals, that is, all radicals of size M1 and larger. Equation 3-22 for the polymerization rate is not directly usable because it contains a term for the concentration of radicals. Radical concentrations are dif cult to measure quantitatively, since they are very low ($ 10 8 M), and it is therefore desirable to eliminate [M ] from Eq. 3-22. In order to do this, the steady-state assumption is made that the concentration of radicals increases initially, but almost instantaneously reaches a constant, steady-state value. The rate of change of the concentration of radicals quickly becomes and remains zero during the course of the polymerization. This is equivalent to stating that the rates of initiation Ri and termination Rt of radicals are equal or

If you share your Word documents with others, you can use the program s Track Changes feature to keep track of what edits others have made, including formatting changes and text additions or deletions. The Track Changes feature uses different colours for each person s edits, making it easy to see who changed what in the document. If you like, you can change the colour used for your edits. When you review the document, you can specify whose edits you want to review, what types of edits you want to see and whether to accept or reject the changes.

Ri Rt 2kt M 2 3-23

(3.101)

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