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range of temperatures and frequencies. Other applications include electrical switch parts, coaxial cable separators, and electroluminescent devices. It is also used in electrostatic dry copying (xerography) machines, a consequence of its photoconductivity.

(3.125) and the Hamiltonian is the 3 x 3 Hermitian matrix (3.126) What about the expectation values. The reader can easily check that the expectation value of the energy [i.e., (3.81) with J1, -+ 0] is given by = where (3.128) Analogously, for the nth component of momentum [Le., (3.94) with

3-14g-3

Poly(N-vinylpyrrolidinone)

J nj;t :t J) ,



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Poly(N-vinylpyrrolidinone) (PVP) is obtained by polymerization of N-vinylpyrrolidinone (LVII). The largest use is in hair sprays and wave sets because of its property as a lm

(3.127)

former, with good adhesion to hair, lm luster, and ease of removal by washing with water. PVP is also used in hand creams and liquid makeups. Aqueous solutions of PVP complexed with iodine (Betadine) are useful in the management of wounds and incisions for preventing infections. PVP also nds applications in the textile industry because of its af nity for many dyestuffs; it is used for dye stripping and in the formulation of sizes and nishes. PVP has also been considered as a blood plasma substitute.

0] we have (3.129)





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You can resize columns and rows to fit the data. Position the over the border of the heading of the column or row that you want to resize. Click and drag the border to the desired size.

Typical chain polymerization systems, both radical and ionic, proceed with accompanying chain-breaking reactions because of the type of propagating centers and/or the reagents

n Jd rJt (~{)~n J).

present. Bimolecular termination and chain transfer are ever present in radical chain polymerization and limit the lifetime of propagating radicals. Chain polymerizations without chain-breaking reactions, referred to as living polymerizations, would be highly desirable because they would allow the synthesis of block copolymers by the sequential addition of different monomers (Eq. 3-215). A reactive species I* initiates polymerization of monomer A.

Now for the angular momentum [Le., (3.95) with J1, -+ 0] we find immediately that the expectation value of the nth component of the orbital angular momentum is given by

An *

Jt (~ nmqxm~ {)~q J) .

An Bm *

(3.130)

3-215

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When the polymerization of monomer A is complete, the reactive centers are intact because of the absence of chain-breaking reactions. Addition of a second monomer B results in the formation of a block copolymer containing a long block of A repeat units followed by a long block of B repeat units. It is possible to continue the sequential propagation by adding a third batch of monomer, or one can terminate the process by the addition of a reagent to terminate the propagating centers. Block copolymers have commercial potential for obtaining products that can incorporate the desirable properties of two or more homopolymers. This potential has led to an intense effort to nd reaction systems that proceed as living polymerizations. Some anionic chain polymerizations proceed as living polymerizations under conditions where no viable chainbreaking reactions occur, and this has resulted in useful block copolymers (Sec. 5-4). The situation is very different for conventional (nonliving) radical polymerizations since the lifetime of propagating radicals in these systems is very short (typically less than a second or, at most, a few seconds) because of the ever-present occurrence of normal bimolecular termination (coupling and/or disproportionation). Living radical polymerizations have been achieved by minimizing normal bimolecular termination and prolonging the lifetime of living polymers into hours or longer through the introduction of dormant states for the propagating species. This is achieved through alternate modes of reaction for the propagating radicals, speci cally, by either reversible termination or reversible transfer. Living radical polymerizations have good commercial potential for materials synthesis because many more monomers undergo radical polymerization compared to ionic polymerization (Sec. 3-1b). Living radical polymerization (LRP) with reversible termination generally proceeds as follows:

But the spin contribution to the angular momentum needs a bit of extra thought, as it involves one of the quatemion units sandwiched by the wavefunction. In terms of components,

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