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mechanical behavior, that is, its deformation and ow characteristics under stress. The mechanical behavior of a polymer can be characterized by its stress strain properties [Billmeyer, 1984; Nielsen and Landel, 1994]. This often involves observing the behavior of a polymer as one applies tension stress to it in order to elongate (strain) it to the point where it ruptures (pulls apart). The results are usually shown as a plot of the stress versus elongation (strain). The stress is usually expressed in newtons per square centimeter (N cm 2 ) or megapascals (MPa) where 1 MPa 100 N cm 2 . The strain is the fractional increase in the length of the polymer sample (i.e., L=L, where L is the original, unstretched sample length). The strain can also be expressed as the percent elongation, L=L 100%. Although N cm 2 is the SI unit for stress, psi (pounds per square inch) is found extensively in the literature. The conversion factor is 1 N cm 2 1:450 psi. SI units will be used throughout this text with other commonly used units also indicated. Several stress strain plots are shown in Fig. 1-10. Four important quantities characterize the stress strain behavior of a polymer: 1. Modulus. L=L. The resistance to deformation as measured by the initial stress divided by



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Feynman's 1986 Dirac Memorial Lecture at Cambridge University [207] gives an insightful account on why there must be antiparticles and on the spinstatistics theorem. 2 and Appendix 3 of the book by Pike and Sarkar [492] will give you a good idea of what the group theory approach to photon localization is about. Jordan's papers [331-336] on this subject are also quite readable as well as the pedagogical paper by Han and Kim on the little group for photons [270]. The key original references are the 1948 paper by Pryce [501], 1949 paper by Newton (no, this is not Isaac!) and Wigner [464], and Wightman's imprimitivity reformulation [643]. Also related to this group theory approach are [32], [645], [647], [648], and the references mentioned in [464]. For those wishing to study group theory in depth, there are many books on the subject. I find the following books particularly useful: [330], [639], [396], and [650].





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2 Ultimate Strength or Tensile Strength The stress required to rupture the sample 3 Ultimate Elongation The extent of elongation at the point where the sample ruptures 4 Elastic Elongation The elasticity as measured by the extent of reversible elongation Polymers vary widely in their mechanical behavior depending on the degree of crystallinity, degree of crosslinking, and the values of Tg and Tm High strength and low extensibility are obtained in polymers by having various combinations of high degrees of crystallinity or crosslinking or rigid chains (charcterized by high Tg ) High extensibility and low strength in polymers are synonymous with low degrees of crystallinity and crosslinking and low Tg values The temperature limits of utility of a polymer are governed by its Tg and/or Tm Strength is lost at or near Tg for an amorphous polymer and at or near Tm for a crystalline polymer.

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and its relativistic wave equation. The paper by Oppenheimer [472], whose philosophy inspired this entire chapter is, of course, a must. The approach presented here has some similarity to that of Good and collaborators [241, 268, 269, 462, 463, 624]. See also Weinberg's approach in [626-628]. If you can read French, have a look at the following papers by Proca: [497-499]. The original paper by Landau and Peierls on the wavefunction of the photon in configuration space [387] is also available in an English translation and is well worth looking at. You might also want to look at Cook's rediscovery of the Landau-Peierls wavefunction [119,120] as well as Inagaki's [310, 311] extension of Cook's work. For an extensive review of the photon wavefunction, see [54]. See also the nice pedagogical discussion in Sec. 1.5.4 of [552].

An almost in nite variety of polymeric materials can be produced The polymer scientist must have an awareness of the properties desired in the nal polymer in order to make a decision about the polymer to be synthesized Different polymers are synthesized to yield various mechanical behaviors by the appropriate combinations of crystallinity, crosslinking, Tg , and Tm Depending on the particular combination, a speci c polymer will be used as a ber, exible plastic, rigid plastic, or elastomer (rubber) Commonly encountered articles that typify these uses of polymers are clothing and rope ( ber), packaging lms and seat covers ( exible plastic), eyeglass lenses and housings for appliances (rigid plastic), and rubber bands and tires (elastomer) Table 1-4 shows the uses of many of the common polymers.

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