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(3.177) where the energy index in the creation and annihilation operators has been dropped for convenience, as we will only deal with positive-energy states now. Now what about the creation and annihilation operators a (p) and a (p) If they A obey the commutation relations (3.178) the particles (our photons) will follow Bose-Einstein statistics. If they obey the anti-commutation relations (3.179) the particles will follow Fermi-Dirac statistics as electrons, for example, do. In 1940, Pauli showed quite generally that particles of integral spin must follow Bose-Einstein statistics, while those of half-integral spin must follow Fermi-Dirac statistics [478]. This is called the spin-statistics theorem. Then, as the photon has spin 1, it follows Bose-Einstein statistics, and aA(p) and a1 (p) must obey the commutation relations (3.178) rather than the anticommutation relations (3.179). What are the second-quantized expressions for the various observables In particular, what is the second-quantized Hamiltonian (i.e., the energy of an arbitrary number of photons) In ordinary many-body second quantization, as is done for the Dirac equation, for example, the second-quantized wavefunction - is also the field operator. In that case, the second-quantized version of a first-quantized operator 0 is given by (3.180) Here we cannot use this expression, because 1p is not the field operator. Recall from Section 3.2 that the wavefunction W is related to the field:F by (3.72). Then the field operator F is given by



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Chem, 73, 95 (1978) Lutz, J-F and K Matyjaszewski, Macromol Chem Phys, 203, 1385 (2002) Lutz, J-F, P Lacroix-Desmazes, and B Boutevin, Macromol Rapid Commun, 22, 189 (2001) Machi, S, J Silverman, and D J Metz, J Phys Chem, 76, 930 (1972) Macosko, C W and D R Miller, Macromolecules, 9, 199 (1976) Madruga, E L and J Sanroman, J Polym Sci Polym Chem Ed, 19, 1101 (1981) Maekawa, T, S Mah, and S Okamura, J Macromol Sci Chem, A12, 1 (1978) Mahabadi, H K, Makromol Chem Macromol Symp, 10/11, 127 (1987) Mahabadi, H K and K F O Driscoll, J Polym Sci Polym Chem Ed, 15, 283 (1977a); Macromolecules, 10, 55 (1977b) Mahabadi, H K and A Rudin, J Polym Sci, 17, 1801 (1979) Manickam, S P, K Venkatarao, U C.

F(r) =





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Singh, and N R Subbaratnam, J Polym Sci Polym Chem Ed, 16, 2701 (1978) Mapunda-Vlckova, J and J Barton, Makromol Chem, 179, 113 (1978)..

You can apply colour bars instead by clicking Data Bars. Excel applies the colour scale to the conditional formatting.

~J d3pv'iHf~ {aA(p) 1P+(p,.x,r,t) + a1(-p) 1P-(p,.x,r,t)},

Martin, J C, Solvation and Association, Chap 20 in Free Radicals, Vol II, J K Kochi, ed, Wiley, New York, 1973 Masuda, S, M Tanaka, and T Ota, Polymer, 28, 1945 (1987); J Polym Sci Polym Chem Ed, 27, 855 (1989) Matheson, M S, E E Auer, E B Bevilacqua, and E J Hart, J Am Chem Soc, 71, 497 (1949) Matsumoto, A and T Kimura, J Macromol Sci Pure Appl Chem, A33, 1049 (1996) Matsumoto, A and T Otsu, Macromol Symp, 98, 139 (1995) Matsumoto, M, K Takakura, and T Okaya, Radical Polymerizations in Solution, Chap 7 in Polymerization Processes, C E Schildknecht, ed (with I Skeist), Wiley-Interscience, New York, 1977 Matsumoto, A, T Kubota, and T Otsu, Macromolecules, 23, 4508 (1990) Matsumoto, A, Y Oki, and T Otsu, Polym J, 25, 237 (1993) Matsumoto, A.

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(3.181) where H is the first-quantized Hamiltonian (3.166). As we saw in Section 3.2, the energy is the time component of the four-momentum, which is given in terms of the

, Y Sano, M Yoshioka, and T Otsu, J Polym Sci Polym Chem Ed, 34, 291 (1996) Matsuo, K, G W Nelb, R G Nelb, and W H Stockmayer, Macromolecules, 10, 654 (1977) Matuszewski-Czerwik, J and S Polowinski, Eur Polym J, 26, 549 (1990) Matyjaszewski, K, ed, Controlled Radical Polymerization, Am Chem Soc Symp Ser, Vol 685, American Chemical Society, Washington, DC, 1998a; Macromol Symp, 132, 85 (1998b); Controlled/ Living Radical Polymerization, Am Chem Soc Symp Ser, Vol 768, American Chemical Society, Washington, DC, 2000; Macromol Symp, 174, 51 (2001); Macromol Symp, 182, 209 (2002) Matyjaszewski, K and J Xia, Chem Rev, 101, 2921 (2001) Matyjaszewski, K, T E Patten, and J Xia, J Am Chem Soc, 119, 674 (1997) Mayadunnee, R T A, J Jeffrey, G Moad, and E Rizzardo, Macromolecules, 36, 1505 (2003).

quaternionic fields by (3.71). Translating this into our present context, the secondquantized Hamiltonian (energy) is given in terms of the field operator by

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