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3-15b-4-b Blocks via Combination of ATRP and Non-ATRP. Block copolymers have also been synthesized via transformation reactions in which not all blocks are produced by ATRP [Kamigaito et al., 2001; Matyjaszewski, 1998b; Matyjaszewski and Xia, 2001]. One approach is to use an appropriate initiator in the non-ATRP polymerization to produce a polymer with a halogenated end group either through initiation or termination. The halogenterminated polymer is then used as a macroinitiator in ATRP. For example, polymers with halogenated end groups are obtained in the cationic polymerization of styrene with 1-phenylethyl chloride and SnCl4 , the anionic ring-opening polymerization of caprolactone with 2,2,2-tribromoethanol and triethyl aluminum, and the conventional radical polymerization of vinyl acetate with a halogen-containing azo compound. Another approach is to use an initiator for ATRP that produces a polymer with a functional group capable of initiating a non-ATRP polymerization. ATRP polymerization of methyl methacrylate with 2,2,2-tribromoethanol produces an HO-terminated poly(methyl methacrylate). The hydroxyl group acts as an initiator in the presence of triethyl aluminum for the ring-opening polymerization of caprolactone. Macroinitiators for ATRP can be produced from polymers obtained from non-ATRP polymerization by appropriate conversion of their end groups. For example, hydroxyl-capped polymers obtained by cationic or anionic chain polymerization or even step polymerization can be esteri ed with 2-bromopropanoyl bromide to yield Br-capped polymers that are ATRP macroinitiators. 3-15b-5 Other Polymer Architectures



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19 Dec 2018 ... Convert Word to PDF programatically [ C# ] with several conversion ... The following code snippet is used to open the Word document with ...

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I don't think there is a free .NET library that you can use. Docentric Toolkit is a .​NET library that you can use to convert a Word document to PDF:

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A star polymer contains polymer chains as arms emanating from a branch point. Star polymers can be synthesized via ATRP by using an initiator containing three or more halogens, for example, a 3-arm star polymer is obtained by using a tribromo initiator:

3-234

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Click and drag the fill handle across or down the number of cells that you want to fill. The changes to .

A graft copolymer is a branched polymer containing a polymer chain derived from one monomer to which are attached one or more polymer side chains of another monomer. ATRP produces a graft copolymer when the initiator is a polymer with one or more halogencontaining side groups:

(2.31)

3-235





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The delta function in (231) is omitted in some elementary textbooks, where pin the x representation is often taken to be just (ijh)8j8x But the delta function in (231) is very important because it tells us that p is diagonal in the x representation This diagonality leads to the elimination of the integrals in (229) when we use (231), yielding the familiar SchrOdingerequation for a particle under the action of a potential V: (232) Some operators in quantum mechanics might not be diagonal in the x representation This is the case of a nonlocal potential considered by Gottfried (see Prob 4 on p 75 of [243]), for example The second thing we should mention is that there is another way in which a classical theory can be quantized This other way uses the older Lagrange formulation of classical mechanics rather than Hamilton's.

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When the polymeric initiator contains many halogens, there will be many grafted side chains, and the product is called a comb or brush polymer. A variety of polymers can be used as the polymeric initiator, including polymers containing vinyl chloride and 4-chloromethylstyrene units, and halogenated natural and butyl rubbers. Graft copolymers are discussed further in Chaps. 5, 6, and 9. Hyperbranched polymers (see structure LXII in Sec. 2-16a) are produced from monomers that contain both a polymerizable double bond and an initiating function, such as p-(chloromethyl)styrene. The product is highly branched with one double bond end group and many

It was developed by Feynman based on a hint he found in one of Dirac's papers For some systems, where no Hamiltonian exists, this kind of quantization is the only alternative Feynman's formulation of quantum mechanics is also very interesting because it shows us what lies beyond the minimal action principle, and in doing so sort of explains why the minimum action principle comes about The minimal action principle is the fascinating idea behind the Lagrangian formulation that the actual motion of a particle, say, is always the one that minimizes a certain "magical" quantity called the action.

chloromethyl end groups; the number of chloromethyl end groups equals the degree of polymerization. This polymerization has been called self-condensing vinyl polymerization (SCVP). Partial dendrimer structures have also been described. The synthesis of complex polymer architectures by ATRP (or other living radical polymerizations) is useful but relatively restricted because the occurrence of bimolecular termination increases with the number of initiator sites on a polymeric species. 3-15c Stable Free-Radical Polymerization (SFRP)

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