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To insert multiple columns and rows, select two or more columns and rows in the worksheet; then activate the Insert command as described in this section. Excel adds the same number of new columns and rows as the number you originally selected.

E(r) = 1d3PV 27:2



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Use free spire.doc library you can simply convert word to pdf without Word: //Load Document. Document document = new Document(); document.LoadFromFile(@"E:\work\documents\TestSample.docx"); //Convert Word to PDF. document.SaveToFile("toPDF.PDF", FileFormat.PDF);

Emulsion polymerization refers to a unique process employed for some radical chain polymerizations. It involves the polymerization of monomers in the form of emulsions (i.e., colloidal dispersions). The process bears a super cial resemblance to suspension polymerization (Sec. 3-13c) but is quite different in mechanism and reaction characteristics. Emulsion polymerization differs from suspension polymerization in the type and smaller size of the particles in which polymerization occurs, in the kind of initiator employed, and in the dependence of polymer molecular weight on reaction parameters.

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Emulsion polymerization was rst employed during World War II for producing synthetic rubbers from 1,3-butadiene and styrene. This was the start of the synthetic rubber industry in the United States. It was a dramatic development because the Japanese naval forces threatened access to the southeast Asian natural-rubber (NR) sources, which were necessary for the war effort. Synthetic rubber has advanced signi cantly from the rst days of balloon tires, which had a useful life of 5000 mi to present-day tires, which are good for 40,000 mi or more. Emulsion polymerization is presently the predominant process for the commercial polymerizations of vinyl acetate, chloroprene, various acrylate copolymerizations, and copolymerizations of butadiene with styrene and acrylonitrile. It is also used for methacrylates, vinyl chloride, acrylamide, and some uorinated ethylenes.

Now use (3.185) and (3.163) to show that u>.(p) = xtu>.(p),

Principles of Polymerization, Fourth Edition. By George Odian ISBN 0-471-27400-3 Copyright # 2004 John Wiley & Sons, Inc.

where u>. (p) is the unit vector u>.(p)

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The emulsion polymerization process has several distinct advantages. The physical state of the emulsion (colloidal) system makes it easy to control the process. Thermal and viscosity problems are much less signi cant than in bulk polymerization. The product of an emulsion polymerization, referred to as a latex, can in many instances be used directly without further separations. (However, there may be the need for appropriate blending operations, e.g., for the addition of pigments.) Such applications include paints, coating, nishes, and oor polishes. Aside from the physical difference between the emulsion and other polymerization processes, there is one very signi cant kinetic difference. For the other processes there is an inverse relationship (Eq. 3-97) between the polymerization rate and the polymer molecular weight. This drastically limits one s ability to make large changes in the molecular weight of a polymer, from 25,000 to 100,000 or from 100,000 to 25,000. Large decreases in the molecular weight of a polymer can be made without altering the polymerization rate by using chain-transfer agents. However, large increases in molecular weight can be made only by decreasing the polymerization rate by lowering the initiator concentration or lowering the reaction temperature. Emulsion polymerization is a unique process in that it affords the means of increasing the polymer molecular weight without decreasing the polymerization rate. Because of a different reaction mechanism, emulsion polymerization has the advantage of being able to simultaneously attain both high molecular weights and high reaction rates. 4-1b 4-1b-1 Qualitative Picture Components and Their Locations

->'xtu>.(p).

The physical picture of emulsion polymerization is based on the original qualitative picture of Harkins [1947] and the quantitative treatment of Smith and Ewart [1948] with subsequent contributions by other workers [Blackley, 1975; Casey et al., 1990; Gao and Penlidis, 2002; Gardon, 1977; Gilbert, 1995, 2003; Hawkett et al., 1977; Piirma, 1982; Poehlein, 1986; Ugelstad and Hansen, 1976]. Table 4-1 shows a typical recipe for an emulsion polymerization [Vandenberg and Hulse, 1948]. This formulation, one of the early ones employed for the production of styrene-1,3-butadiene rubber (trade name: GR-S), is typical of all emulsion polymerization systems. The main components are the monomer(s), dispersing medium, emulsi er, and water-soluble initiator. The dispersing medium is the liquid, usually water,

Cavity Quantum Electrodynamics: The Strange Theory of Light in a Box Sergio M. Dutra Copyright 2005 John Wiley & Sons, Inc.

TABLE 4-1 Composition of a GR-S Recipe for Emulsion Polymerization of Styrene-Butadienea Component Styrene Butadiene Water Emulsi er (Dresinate 731) n-Dodecyl mercaptan NaOH Cumene hydroperoxide FeSO4 Na4 P2 O7 10 H2 O Fructose

Data from Vandenberg and Hulse [1948].

To open the Insert dialog box, click a cell, click the Insert on the Home tab and click Insert Cells.Then click Entire Row or Entire Column and click OK. Excel adds a row or column above or to the left of the active cell.

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