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The applications of activation analysis are almost innumerable. In the physical sciences, activation analysis is used in trace-element analysis of semiconductor materials, metals, meteorites, lunar samples, and terrestrial rocks. In most cases, the multielemental analysis feature of activation analysis is used to measure the concentrations of several trace-elements simultaneously. From these detailed studies of trace-element abundance patterns, one has been able to deduce information about the thermal and chemical history of the Earth, moon, Mars, and meteorites, as well as the source or age of an object. The use of activation analysis in criminal investigations ( forensic activation analysis) is also well established. The basic idea here is to match the traceelement distributions found in bullets, paint, oil, and so on found at the scene of a crime with the trace-element distributions in objects found with criminal suspects. Such identi cation is rapid and nondestructive (allowing the actual evidence to be presented in court). Moreover, the probability of its correctness can be ascertained quantitatively. Other prominent examples of the use of forensic activation analysis involve con rmation of the notion that Napoleon was poisoned (by nding signi cant amounts of arsenic in hair from his head) and the nding that the activation analysis of the wipe samples taken from a suspect s hand can reveal not only if he or she has red a gun recently but also the type of gun and ammunition used. Applications of activation analysis in the environmental sciences are routine. Determinations of the trace element content of urban atmospheres, lakes, streams,





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The structure of 1,3-difluoropropane has been investigated by Klaboe et al. (1982). IR spectra were obtained of the compound as a vapor, in solution, and of the unannealed and annealed solid between 4000 and 30 cm I . Raman spectra were recorded of the liquid and of the unannealed and the annealed solid. The authors show that in the vapor phase the compound exists in at least three conformations. The ratios of the conformational abundance are given in brackets GG(63), AG(27) and GG"( 10). The dominant GG conformer is the one which persists in the crystalline state, too. Durig and Little ( 1981) determined the conformational barriers to internal rotation of methyl vinyl ketone by IR and Raman spectroscopy. They recorded IR spectra of the gaseous and the solid states and the Raman spectrum of the liquid state. They also determined the potential function for internal rotation of the asymmetric top and obtained the following potential constants: V1 = 180 f 9, V 2 = 827 f 107, V3 = 113 I 8, and V4 = 150 5 34 cm I. According to these data, the s-ti-uns conformer is the predominant form at ambient temperature, and the enthalpy difference between the s-ti~ansand the s-cis conformer in the gas phase is 280 cm I. The relative intensities of the Raman bands as a function of the temperature afford an enthalpy difference of 172 cm for the liquid.

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