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For a long time it has been known that anisotropic molecules, the so-called mesogenic groups, can form LC phases. The LC phases are thermodynamically stable phases that exist in a temperature range between the crystalline phase and the isotropic melt. The remarkable properties of LC phases stem from their combination of long-range order of crystals with mobility of uids, such as birefringence, uidity, and alignment change by external elds. LC polymers are well-known polymer materials that combine the self-organization of the mesogenic groups into the ordered structure of LC phases with some typical polymer properties. For example, above the glass transition temperature (Tg), these polymers are in the LC state and can be ordered by electric or magnetic elds. Cooling down below Tg, the system vitri es yielding anisotropic glasses. This makes the material suitable for optical applications and for storage devices. LCEs are unique because of the combination of the anisotropic aspects of the LC phases and the rubber elasticity of polymer networks. Because of the LC properties, mesogens in LCEs show alignment, and the alignment of mesogens can be coupled with polymer network structures. This coupling gives rise to many characteristic properties of LCEs. There are a number of excellent books and review articles on the chemistry, physics, and theory of LCEs (Xie and Zhang, 2005; Warner and Terentjev, 2003; Terentjev, 1999; Brand, 1998; Cotton and Hardouin, 1997; Warner and Terentjev, 1996; Kelly, 1995; Zentel, 1989). LCEs have been a hot topic recently because large deformations of LCE materials can be induced by changing the alignment of mesogens in LCEs by external stimuli such as electric elds, changes in temperature, and light. These characteristics make LCEs extremely useful as raw materials for arti cial muscles and soft actuators.



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of the plaintext language, eg, knowing that the letters "e" and "t" are the most frequently occurring letters in typical text (accounting for 13% and 9% of letter occurrences), and knowing that particular two- and threeletter occurrences of letters appear quite often together (eg, "in", "it", "the" "ion", "ing", etc) make it relatively easy to break this code If the intruder has some knowledge about the possible contents of the message, then it is even easier to break the code For example, if Trudy the intruder is Bob's wife and suspects Bob of having an affair with Alice, then she might suspect that the names "bob" and "alice" appear in the text" If Trudy knew for certain that those two names appeared in the ciphertext and had a copy of the example ciphertext message above, then she could immediately determine 7 of the 26 letter pairings, since "alice" is the only five-letter word in the message, and "bob" is the only three-letter word that has an identical first and last letter Thus, Trudy requires 109 fewer possibilities to be checked a by brute force method Indeed, if Trudy suspected Bob of having an affair, she might well expect to find some other choice words in the message as well When considering how easy it might be for Trudy to break Bob and Alice's encryption scheme, one can distinguish three different scenarios, depending on what information the intruder has:

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LCEs are usually lightly cross-linked networks. The cross-linking density is known to have a great in uence on the macroscopic properties and the phase structures (Kupfer et al., 1994; Finkelmann and Rehage, 1984). The mobility of chain segments is decreased with an increase in the cross-linking points, and consequently the mobility of mesogens in the vicinity of a cross-link is suppressed. A cross-link is recognized as a defect in the LC structure, and an increase in the cross-linking density produces an increasing number of defects. Therefore, LC polymers with a high cross-linking density are referred to as LC thermosetting polymers (duromers), which are distinguished from LCEs.

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