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A review is available for aminomethylation, also called hydroaminomethylation or aminocarbonylation, including more recent developments 29 The application of various ruthenium compounds in acetonitrile330 or rhodium and ruthenium catalysts or their mixtures 33 ! was found to show significant improvements (high product selectivities, high linearities) in the aminomethylation of terminal alkenes to produce tertiary amines. New examples, particularly those by Eilbracht, clearly demonstrate the synthetic potential of this process. Symmetrically and unsymmetrically substituted secondary and tertiary amines are produced selectively from alkenes, CO, and hydrogen in the presence of [Rh(COD)Clh catalyst precursor 32-334 There have been developments with respect to the synthesis of aliphatic primary amines from terminal alkenes, synthesis gas, and ammonia 35,336 The first efficient aminomethylation allows the production of industrially important, low-molecularweight linear primary amines 36 The use of a Rh-Ir dual-catalyst system in the aminomethylation of propene, I-butene, and I-pentene under hydroformylation conditions in an aqueous two-phase system gives amines in better than 70% yield. Selectivity to the primary amines could be improved to above 90% by lowering the polarity of the organic phase. This was explained by a higher efficiency of a solvent of low polarity to remove the primary amine from the catalyst-containing aqueous medium. As a result, the primary amine no longer competes with ammonia. The improved catalyst performance is also attributed to the high activity of Ir to hydrogenate the C-N double bond of the imine intermediate. Excellent (99 : I) normal to iso selectivities could be achieved by applying the ligand BINAS [prepared by the direct sulfonation of I, I'-binaphthaline-2,2-diylbis(methylene)bis(diphenylphosphane)].



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16.1 16.2 16.3 16.4 16.5 16.6 16.7

N secondary axes.xls Contains charts that use secondary axes N series in different sheets.xls Contains a chart that uses data contained

=RIGHT(A1,LEN(A1)-FIND( * ,SUBSTITUTE(A1, , * ,LEN(A1)LEN(SUBSTITUTE(A1, , )))))

n Type a hexadecimal color number directly into the Text Color text field n Type a color name directly into the Text Color text field n Select the color box to open the color picker

Biogeochemical agents often have not yet been cultured because habitats are so poorly understood, so dif cult to simulate Large- and small-scale habitat diversity may select for many different agents within exible ecological guilds that carry out processes Relatively low chance of isolating ecologically signi cant agents because community diversity is immense Process may stem from many cooperating populations





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3. If you want to link this optional region to the state of another optional region, from the Advanced tab, follow these steps:

You also can create channels at runtime for use with the Message Service, Proxy Service, and Data Management Service when using LiveCycle Data Services or BlazeDS. n

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Most of the ink irreversibly redeposited in recycling operations is deposited inside the ber lumen (Ben and Dorris, 1999) with the extent of redeposition affected by the mixing action imparted during suspension processing (Bennington and Wang, 2001). Lumen loading of ink is undesirable, as it cannot be removed subsequently. However, lumen loading can be used to enhance certain sheet properties. In papermaking, it is often desirable to load the sheet with ller materials to enhance their optical properties. However, ller that remains on exterior ber surfaces interferes with bonding and reduces the physical strength properties of the paper. Processes to load the ller inside the ber lumen allow the bene ts of increased ller levels to be realized without compromising the strength properties of the sheet. Lumen loading is facilitated by the high-shear mixing of pulp in an excess of ller material. As shear increases, so does the level of mechanical action. This causes more ller to enter and remain in the lumen (Middleton and Scallan, 1993). No commercial application for intentional lumen loading of pulp bers is currently operated.

The array formula is entered into all the selected cells and returns the count of values in the Data range that fall into each bin. You can then create other formulas that make use of the frequencies. For example, column E displays cumulative frequencies, and column F shows cumulative percent. The combination chart was created using the frequency data in column D (the column series) and the cumulative percent data in column F (the line series). The histogram suggests that the data approximates a normal distribution.

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