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Accept: text/html, image/gif, image/jpeg Second, the Web server sends a response message with the object to the client: HTTP/10 200 OK Date: Wed, 12 Aug 1998 15:39:29 Server: Apache/130 (Unix) Last-Modified: Mon, 22 Jun 1998 09:23:24 Content-Type: image/gif data data data data data The client displays the object to the user but also saves the object in its local cache Importantly, the client also caches the last-modified date along with the object Third, one week later, the user requests the same object and the object is still in the cache Since this object may have been modified at the Web server in the past week, the browser performs an up-to-date check by issuing conditional GET Specifically, the browser sends GET /fruit/kiwigif HTTP/10 User-agent: Mozilla/40 Accept: text/html, image/gif, image/jpeg If-modified-since: Mon, 22 Jun 1998 09:23:24 Note that the value of the If-modified-since: header line is exactly equal to value of the Last-Modified: header line that was sent by the server one week ago This conditional GET is telling the server to only send the object if the object has been modified since the specified date Suppose the object has not been modified since 22 Jun 1998 09:23:24 Then, fourth, the Web server sends a response message to the client: HTTP/10 304 Not Modified Date: Wed, 19 Aug 1998 15:39:29 Server: Apache/130 (Unix) (empty entity body) We see that in response to the conditional GET, the Web server still sends a response message, but it doesn't bother to include the requested object in the response message Including the requested object would only waste bandwidth and increase user perceived response time, particularly if the object is large (such as a high resolution image) Note that this last response message has in the status line 304 Not Modified, which tells the client that it can go ahead and use its cached copy of the object.



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its hydrolysis is much easier than the ester groups linked to azobenzene moieties However, it was found that the reaction is not trivial Under the used conditions, with which PAzoMA was not affected by the hydrolysis reaction, a complete (100%) removal of tBA groups is not possible The hydrolysis of PtBA-bPAzoMA actually results in a hydrophilic block that is a random copolymer of tert-butyl acrylate and acrylic acid, P(tBA-co-AA) The obtained diblock copolymer P(tBA-co-AA)-b-PAzoMA can form core shell micelles and vesicles depending on the preparation conditions And the incomplete hydrolysis of PtBA, which weakens the hydrophilicity of the hydrophilic block, was believed to play an important role in the effective dissociation and reformation of the micellar aggregates upon UV and visible light exposures By means of ATRP, the hydrolysis of PtBA remains the general route to the use of PAA as the hydrophilic block.





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A Web cache -- also called a proxy server -- is a network entity that satisfies HTTP requests on the behalf of a client The Web cache has its own disk storage, and keeps in this storage copies of recently requested objects As shown in Figure 22-4, users configure their browsers so that all of their HTTP requests are first directed to the Web cache (This is a straightforward procedure with Microsoft and Netscape browsers) Once a browser is configured, each browser request for an object is first directed to the Web cache As an example, suppose a browser is requesting the object http://wwwsomeschooledu/campusgif

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Another example of azobenzene amphiphilic BCP whose hydrophilic block was prepared through two steps is also depicted in Fig 62 (structure c) (Qi et al, 2008), namely, quaternized poly(4-vinyl pyridine)-b-poly {6-[4-(4-ethoxyphenylazo)phenoxy]hexyl methacrylate} (QP4VP-b-PAzoMA) To obtain this BCP, chlorine-terminated poly(4-vinyl pyridine) (P4VP) was rst synthesized and then used to initiate the polymerization for PAzoMA The resulting diblock of P4VP-bPAzoMA was subjected to a quaternization reaction using bromoethane to obtain the amphiphilic BCP Other azobenzene amphiphilic BCPs prepared using ATRP whose hydrophilic block is not PEO were also reported (Ravi et al, 2005) We note that this chapter concerns only amphiphilic BCPs and does not cover the numerous works of azobenzene BCPs, including the early syntheses using other polymerization techniques, which was reviewed elsewhere (Zhao, 2007a).

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