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The observed normal vibrations are a linear combination of these degrees of freedom. In addition, combinations of normal vibrations may be visible, i.e., harmonics, sum and difference tones . Combination tones usually show weak bands. An overtone (of a deformation) vibration which has about the same frequency as a fundamental (stretching) vibration of the same bonds may mix with the fundamental to produce two bands of nearly equal intensity. This effect, which may produce supernumerary bands is called Fermi resonance (Fermi, 1931). A necessary condition for Fermi resonance is that the overtone and the fundamental must belong to the same symmetry species (see Sec. 2.7). If a molecule is already in a vibrational excited state when it undergoes a further excitation, a hot band may be observed which due to anharmonicity has a lower frequency compared to the transition from the ground state. Some characteristic vibrations have been given special descriptive names (Mecke 1932). Stretching vibrations of an XY group are called v(XY), symmetric defonnation (or scissoring) vibrations of XY2 or XY3 groups are referred to as 6(XY2) or 6(XY3), other deformation vibrations are called wagging w(XY,), rocking p(XY2), or twisting 7 (XU,). Vibrations of CH2 and CH3 groups are shown in Fig. 4.1-1 (Section 4.1). Deformation vibrations of an atom out of a plane defined by three neighboring atoms are called out-of-plane vibrations y. An example is the y(C-H) vibration of the hydrogen atoms on a benzene ring. If in-plane and out-of-plane deformations of heavy atoms are described (instead of H atoms) A and r may stand for 6 and y.





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The central feature of b decay is that, for example, in the b2 direction, the decay converts a neutron into a proton at a constant mass number This conversion will clearly change the number of pairs of like nucleons in the nucleus, and we have already seen that unpaired nucleons in uence the overall stability b Decay in even mass chains will convert odd odd nuclei into the even even isobar with potentially large Q values due to a gain of twice the pairing energy The large Q values lead to high-energy b particles and rapid decays, but the relative stability of the daughter may be less than that of the parent The large Q values also allow the population of higher lying states in the daughter.

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If the nuclei are far from the (most) stable isobar, the decay may have suf cient energy to populate states in the daughter that are above the separation energy 90 Sr provides an example of a change in relative stability following b decay This even even parent is an important ssion product that has a 29-y half-life It decays to the odd odd 90Y, which then decays to the stable isobar 90Zr with a half-life of only 64 h Thus, a pure preparation of 90Sr will come into equilibrium with its daughter after about a week, and the observed activity will be the sum of the two decays A chemical separation can be used to strip out the daughter activity The daughter will decay away in the separated sample and will grow back into the parent sample.

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