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would enable the derivative to be more stable. In fact, the sodium salts of compounds 130, 131 are much less active than sodium artesunate and their solubility in water is still poor.189 Lin et al. prepared compound 132, 133 and found the sodium salt of artelinic acid (133) to be stable in aqueous solution.190,191 However, no report about its clinical trial was publish (Structure 5-12). To search for stable, water-soluble dihydroartemisinin derivatives with higher ef cacy and longer plasma half-life than artesunate and artelinic acid, deoxoartelinic acid 134 was prepared (Scheme 5-18) and tested in vitro and in vivo.192 It was reported that 134 showed superior antimalarial activity and was more stable in simulated stomach acid than arteether. In 1992, Haynes et al. already reported on the synthesis of 5-carba-4-deoxoartesunic acid (135) from artemisinic acid (20) in a similar way, but they did not mention its activity at that time.176

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You are no longer in the declarations section of the module; you are now in an actual procedure. Now you can enter the lines of code needed for your procedure. Enter the following lines of code into the module:

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15 Li, Y; Wu, Y L An over 4-millennium story behind qinghaosu (artemisinin) a fantastic antimalarial-drug from a traditional Chinese herb Curr Med Chem, 2003, 10(21): 2197 2230 16 O Neill, P M; Posner, G H A medicinal chemistry perspective on artemisinin and related endoperoxides J Med Chem, 2004, 47(12): 2945 2964 17 Liang, X T; Yu, D Q; Wu, W L; Deng, H C The structure of yingzhaosu A Huaxue Xuebao (Acta Chimica Sinica), 1979, 37: 215 230 18 Shanghai Institute of Materia Medica, Shanghai 14th Pharmaceutical Plant Studies on the active principles of Shian-Ho-Tsao 1 The isolation, structure and synthesis of Agrimol C Huaxue Xuebao, 1975, 33: 23 33 19 Chen, C L; Zhu, D Y; Wang, H C Huang, B S; Qin, G W The structures of Agrimol A, B, and D.

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Huaxue Xuebao, 1978, 36: 35 41 20 Qin, G W; Chen, Z X; Wang, H C; Qian, M K The structure and synthesis of robustanol A Huaxue Xuebao, 1981, 39: 83 89 21 Zhao, Y; Zheng, J J; Huang, S Y; Li, X J; Lin, Q Y; Zhang, Q X Experimental studies on antimalarial action of protopine derivatives Chin Pharmaceu Bull, 1981, 16: 327 330 22 Lin, L Z; Zhang, J S; Chen, Z L; Xu, R S Studies on chemical constituents of Brucea javanica (L) Merr1 Isolation and identi cation of bruceaketolic acid and other four quassinoids Huaxue Xuebao, 1982, 40: 73 78 23 Han, G Y; Xu, B X; Wang, X P; Liu, M Z; Xu, X Y; Meng, L N; Chen, Z L; Zhu, D Y.

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