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In the case of the direct HCN synthesis and water-gas shift reactions, the temperature range of interest for adsorptive reactor operation (i.e., > 350 C) lies at the upper limit at which chemisorption be used effectively. If the temperatures are much higher, one is forced to use gas solid reactions to attain reasonably high adsorptive capacities at the cost of a more demanding regeneration procedure. Whereas the partial pressure over an adsorbent depends on both its temperature and the adsorbate loading, the dissociation pressure above a decomposing solid is a function of the temperature alone (Fig. 7.9). A reduction in the partial pressure of the adsorptive at a given temperature will thus merely result in a diminished loading for an adsorbent but the complete breakdown of a solid compound with which it was previously in equilibrium, and vice versa, leading to the development of completely different breakthrough front structures. A modified hydrotalcite adsorbent (magnesium aluminum hydroxycarbonate Al2Mg6(OH)16CO3.4H2O) doped with potassium carbonate to enhance its alkalinity has been proposed for carbon dioxide capture at temperatures of around 400 C [34, 35]. By preparing this material according to a published recipe [36], we were able to demonstrate that the kinetics of CO2 adsorption are adequate to keep pace with the rate of the water-gas shift reaction. A major drawback is, however, the extremely low loading capacity of < 2 wt%. Although we only achieved around half of the published values for the commercial product, even these would be incapable of providing cycle times of more than a few minutes at the space times characteristic



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The most flexible way to view your tasks is using Task view, as explained earlier in this chapter. You can also have Outlook display tasks on the To-Do Bar and in Calendar view.

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As demonstrated, depending on the commonality of the data set, pre x compression can signi cantly compress the data without any loss of data delity. In this simple example, pre x compression alone reduced the data from 42 bytes to 29 bytes, saving 30%. Notice that in this example, one value, Paul, doesn t match the pre x at all. It s stored as 0Paul, which increases the length. If this is the case for most of the rows, and pre x compression offers no bene t for a given column, the storage engine will leave the anchor row null and not use pre x compression for that column. This is one reason why sometimes tables will actually grow when compressed.

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fied of dragging the icon of their floppy disk to the trash can icon on the desktop to eject it from the computer for fear of deleting it in the same way files are when placed in the trash can. The conceptual confusion arises because the designers opted to use the same action (dropping) on the same object (trash can) for two completely different operations, deleting and ejecting. Another problem is that not all tasks can be described by objects and not all actions can be done directly. Some tasks are better achieved through issuing instructions and having textual descriptions rather than iconic representations. Imagine if email messages were represented as small icons in your mailbox with abbreviations of who they were from and when they were sent. Moreover, you could only move them around by dragging them with a mouse. Very quickly they would take up your desk space and you would find it impossible to keep track of them all.

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