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Encode Bar Code In Visual C# Using Barcode . Scanning USS Code 39 In .NET Using Barcode decoder for . Studies investigating the origin of this contamination unraveled that the contamination with N-nitrosamines arose during thermal treatment of he malt (kilning). Precursors of NDMA in malt are hordenin, gramine, and dimethylamine, the latter in concentrations of 5.5 12 mg/kg (15). Hordenin and gramine are naturally occurring alkaloids with a tertiary amine structure and are produced in barley during germination processes. Their nitrosation leads to the formation of NDMA. Gramine is converted more rapidly than hordenin; however, hordenin concentrations are higher (43). It has been found that the heating technique is of major importance. Heating the air in the kilning process by direct ring resulted in substantial higher amounts of NDMA in the malt (up to 1080 g/kg) compared with indirect heating using heat exchanger technology (44). In particular, gas burner ames operating at high temperatures (>1500 C) generate substantial amounts of nitrogen oxides from atmospheric nitrogen in the drying air. NOx react with the precursor amines in the malt and this entails markedly increased NDMA formation in the kiln. Modi cations in the ring technique (e.g., lower operating temperatures and indirect heating) reduced NOx generation and therefore NDMA formation (16, 22). Table 4.1.3 shows the trend of NDMA concentrations in beer in Germany from 1977 to 1990. A similar decrease of NDMA concentrations in beer was subsequently observed also in other countries (see Table 4.1.4). 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