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difference in the magni cation of the two images. The important consideration is that the subtracted and added irradiances in the two measured images must correspond to the same point (x, y) on the pupil. The measurements of the irradiance have to be made close enough to the pupil, so that the diffraction effects are negligible, and the geometric approximation remains valid. Let us assume that the wavefront to be measured has some corrugations and deformations of scale r0 (maximum spatial period). With the diffraction grating equation, we see that these corrugations spread out the light over a narrow cone with an angular diameter a l=r0. Thus, the illumination in the plane of observation can be considered a blurred pupil image. Let us now impose the condition that the maximum allowed blurring at a distance z is equal to r0/2. With this condition it is possible to show that the geometrical optics approximation implied in the transport irradiance equation is valid only if z is suf ciently small, so that the following condition is satis ed: r2 11:25 z ( 0 2l It is interesting to see that this distance z is one fourth of the Rayleigh distance in Talbot autoimaging. This result is to be expected, since then the shadow of the grating is geometrical. If the light angular diameter spread a is known, for example, if this is equal to the atmospheric light seeing in a telescope, we may also write z ( l 2a2 11:26

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atomic resolution laterally) For the electron tunneling to take place, both the sample and the tip must be conductive Therefore, STM cannot be used on insulating materials The STM technique can image a sample surface in either constant-current mode or constant-height mode In constant-current mode, in order to keep the tunneling current constant, STM uses feedback to adjust the height of the scanner at each measurement point, for example, when the system senses a tunneling current increase, it adjusts the voltage applied to the piezoelectric scanner so that the scanner lifts the tip and gives an increase in the tip sample distance The scanner height measured at each location on the sample surface constitutes the topographic image.

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Ionic: strong Coulomb interaction among negative atoms (have an extra electron each) and positive atoms (lost an electron). Atomic bonds where electrons are transferred between the constituent atoms of a compound. Typically, ionic bonds are formed between metallic atoms having extra electron to share and nonmetallic atoms that are electron de cient. Covalent: electrons are shared between the molecules, to saturate the valency. Atomic bond where electrons are shared. If the atoms in proximity share a pair of electrons, then the covalent bond is called a single covalent bond. If the atoms in proximity share two or three pairs of electrons, then the covalent bond is called double or triple covalent bond, respectively. Metallic: the atoms are ionized, loosing some electrons from the valence band. Those electrons form a electron sea, which binds the charged nuclei in place. Situation (occurring in metals only) where the valence electrons of metal atoms are shared by more than one neighboring atom. The metal atoms are held together by a sea of electrons oating around. Secondary Bonding

If pn = Ew, = gn(8) is substituted in (3.22), the resulting expression shows the dependence of the probability density function p ( w ;8 ) on the parameters 8:

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Comparison of the efficiency of a maximum likelihood estimator and an ordinary least squares estimator for correlated, normally distributed observations.

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